2022年2017届高考化学一轮复习专题7《有机化学基础》31《有机推断与有机合成》试题 .pdf

20XX届江苏省高考化学一轮复习专题7 课时31 有机推断与有机合成1(2015 南通二模)罂粟碱是一种异喹啉型生物碱，其盐酸盐可用于治疗脑血栓、肢端动脉痉挛等。罂粟碱的合成方法如下：(1)B分子中的官能团有和。(填名称)(2)D E 的转化属于(填反应类型)反应。(3)E和 F发生取代反应生成G的同时有 HCl 生成，则 F的结构简式是。(4)E的同分异构体有多种，写出一种符合下列要求的同分异构体X的结构简式：。.含氧官能团种类与D相同.核磁共振氢谱图中有4个吸收峰.属于芳香族化合物，苯环上一取代物有两种2(2013 江苏高考)化合物 A(分子式为 C6H6O)是一种有机化工原料，在空气中易被氧化。A的有关转化反应如下(部分反应条件略去)：已知：R BrRMgBr(R表示烃基，R和R 表示烃基或氢)(1)写出 A的结构简式：。(2)G是常用指示剂酚酞。写出G中含氧官能团的名称：和。(3)F和D互为同分异构体。写出反应EF 的化学方程式：。3(2015 江苏高考节选)化合物 F是一种抗心肌缺血药物的中间体，可以通过以下方法合成：已知：RCH2CNRCH2CH2NH2，请写出以为原料制备化合物的合成路线流程图(无机试剂可任选)。合成路线流程图示例如下：CH3CH2OH4(2014 江苏高考)非诺洛芬是一种治疗类风湿性关节炎的药物，可通过以下方法合成(部分线路)：14142BC HO文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5根据已有知识并结合相关信息，写出以为原料制备的合成路线流程图(无机试剂任用)。5.(2015新课标卷)A(C2H2)是基本有机化工原料。由A制备顺式聚异戊二烯的合成路线(部分反应条件略去)如下：A顺式聚异戊二烯参照异戊二烯的上述合成路线，设计一种由A和乙醛为起始原料制备1，3-丁二烯的合成路线。6.(2015扬州一模)药物 F具有抗肿瘤、降血压、降血糖等多种生物活性，其合成路线如下：已知：+ClCH2CH3+HCl。以和苯、乙醇为原料，可合成，写出合成流程图(无机试剂任用)。7.(2013江苏高考)已知：，写出以苯酚和HCHO 为原料制备的合成路线流程图(无机试剂任用)。文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I58.(2015南京二模)有机物 H是一种新型大环芳酰胺的合成原料，可通过以下方法合成：F 已知：苯胺有还原性，易被氧化；硝基苯直接硝化的主要产物为间二硝基苯。对苯二胺()是一种重要的染料中间体。根据已有知识并结合相关信息，写出以苯、(CH3CO)2O及CH3COOH 为主要有机原料制备对苯二胺的合成路线流程图(无机试剂任用)。9.(2015南通二模)罂粟碱是一种异喹啉型生物碱，其盐酸盐可用于治疗脑血栓、肢端动脉痉挛等。罂粟碱的合成方法如下：文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5已知：(R、R为烃基)。根据已有知识并结合相关信息，写出以乙醇为原料制备的合成路线流程图(无机试剂任用)。10.(2016 南京、盐城一模)F(4-苯并呋喃乙酸)是合成神经保护剂依那朵林的中间体，某种合成路线如下：(1)化合物 F中的含氧官能团为和。(填官能团的名称)(2)试剂 X分子式为 C2H3OCl且分子中既无甲基也无环状结构，则X的结构简式为；由EF 的反应类型为。(3)写出同时满足下列条件的E的一种同分异构体的结构简式：。.能发生银镜反应.分子中含有 1个苯环且有 3种不同化学环境的氢(4)请写出以和BrCH2COOC2H5为原料制备的合成路线流程图(无机试剂可任选)。合成路线流程图示例如下：CH3CHOCH3COOHCH3COOCH2CH311.(2014 南京模拟)碘海醇是一种非离子型造影剂。下面是以化合物A(分子式为 C8H10的苯的同系物)为原料合成碘海醇的合成路线为：ABCD E 文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5F G H(碘海醇)(1)写出 A的结构简式：。(2)反应 中，属于取代反应的是(填序号)。(3)写出 C中含氧官能团的名称：硝基、。(4)已知：+NaOHR1COONa+R2NH2；呈弱碱性，易被氧化。请写出以和(CH3CO)2O为原料制备染料中间体的合成路线流程图(无机试剂任用)。合成路线流程图示例如下：CH3CH2BrCH3CH2OH 12.(2016南通模拟)A B C D E 文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5F(1)化合物 A中的含氧官能团有、(填名称)。(2)已知：B?C为取代反应，其另一产物为HCl，写出 X的结构简式：。(3)反应 D?E的反应类型是。(4)写出同时满足下列条件的B的同分异构体的结构简式：。.属于芳香族化合物.分子中有 4种不同化学环境的氢.不能与 FeCl3溶液发生显色反应，但能发生水解反应(5)已知：。结合流程信息，写出以对甲基苯酚和上述流程中的X为原料，制备的合成路线流程图(无机试剂任用)。合成路线流程图示例如下：CH3CH2BrCH3CH2OH 13.某芳香烃 A(相对分子质量为92)是一种重要的有机化工原料，以它为初始原料经过如下转化关系(部分产物、合成路线、反应条件略去)可以合成阿司匹林、扁桃酸等物质。其中D能与银氨溶液发生银镜反应。已知：.(苯胺，易被氧化).(X 为 Cl或Br).大多数苯的同系物易被酸性KMnO4氧化为苯甲酸(1)B 的结构简式为。C转化为 D的反应类型为。文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 ZV4S9U6Z6I5(2)反应和顺序能否对换?(填“能”或“不能”)；理由是。(3)写出反应的化学方程式：。14.(2015唐山二模改编)某课题组以甲苯为主要原料，采用以下路线合成化妆品防霉剂对羟基苯甲酸乙酯：高分子化合物是一种建筑材料，根据题中合成路线信息，以甲苯为原料合成该高分子化合物，请设计合成路线(无机试剂及溶剂任选)。合成路线流程图示例如下：CH2CH2CH3CHOCH3COOH15.(2015南通三模)有机物 H是合成免疫抑制剂药物霉酚酸的中间体，可由如下路径合成得到。文档编码:CY7R1N9O3V4 HY5Z8G8Y9O6 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