江苏省淮阴中学2019届高三第一学期化学期末模拟试卷39016.pdf

2019H:1 C12 N 14 O 16 S 32 Na 23 Fe 56 I 127 I421A B12C14CCD 2 C.37D 3A B C()COD 21%4 A-HBrC.5A B H1N1CD 6A.AG=lgc(H+)/c(OH-)=10 Fe2+K+NOSQ2-B.NHHCOAI6HCOBsTNO-C.NH+NaSQ2Cl-D.K+NH+SO2：SA.HFH!B.D.Q 7NAA 25CpH 7NH4CINH3?H2O0H107 NA B NO0211.2 L0.75 NAC.14gCnH2nCCNA/nD.2.7g100mL2 mol L 10.3NA7428208A C17H16NO5B 9CD 9A 2H+2Cl-B.Ca(HCO3)2NaOHCa2+HCO3-+OH-CaCO3j+H2O C.NaHCO3 NaAIO?AIO 2+HCO 3-+H2O=Al(OH)3J+CQ2-D Na2FeO4 Fe2(SO4)34FeO42-+20 H+=4Fe3+3O2 T+10H 2O 10DDFC CH3OCH3+3O2 2CO2+3H2O,.，A aB baC4H+O2+4e=2H2O D,1mol6mol11ABCD3210ACBACBDA C D B AB D BCC3H AD BDBD12A 10CpH=12NaOH40CpH=12NaOHc(H+)B25CpH=10 NaOH pH=10 c(Na+)=c(NH 4+)3=H2T+Qf arC CH3COOH CH3COONa-+C(CH3COO-)+2C(OH)=2 c(H)+c(CH3COOH)D0.1mol 1(NH4)2Fe(SO4)2+2+1 c(NH 4)+c(NH 3 H2O)+c(Fe)=0.3 mol L 613KspcaSO4=9 10 CaSO4 A CaSO4c Ca2+c SO42Bbc(SO42)3 1 3 10 mol L C.dcD.aKspcKsp 141LA(g)B(g)xC(g)H V 0c(A)tAx1 B c(A)C D 2molA2molB0.7moln(B)1.4mol U15HQCr(W)4 103 2 1 c(S0)/mol L 2molA2molB 1molA1molB(Cr2Q(Nib0 CCl457.6 C,CCl4 CrCl3400C,CCl4650C 150mLCC4CCb5060CCrCCCI4TT _ 4Cr2Q+3CCI 4 T 2CrCI 3+3COCI2COC2CHoO50.3300g250mL25.00mL（）1gNa2Q2mol/LH2SQ CDO2-1.1gKI51mL0.0250moI/L24.00mLC2O+61+14H=2Cr+31 2+7H2O,2NSQ+12=NS4Q+2Nal CrCl3NatQ 16SO2MnO2SiO2Fe2O3Al 2O3 SO2 MnO2Na2CO3pH3.7 pH6.57.2NH4HCO3 Fe(OH)3Fe(OH)2Mn(OH)2pH2.77.68.3pH3.79.69.8 _ _ MnSO4+S02-MnS2O6H _ 0 vMnS2O6 _ MnO 24 6070 C,5MnCO 317CO2SO2NOxCO2SO2NOxCO2SO2ab cd 1 pHMnS.0.NOx()H+SO2CO2SO2ACO2BCCH3OHASO2BO2,CH2SO4C100mL10mol/LH 2SO4 ASO21L/min 18CO COCC 5 1100C FeO(s)CO(g)=Fe(s)CO(g)K=0.4 7.2gFeO4.48LCO()1100CFeO19Fe2C3(s)+3CO(g)=2Fe(s)+3CO 2(g)-1 H1=-26.7kJ mol3Fe2C3(s)+CO(g)=2Fe3O(s)+CO(g)-1 H2=-50.8kJ molFe3O(s)+CO(g)=3FeO(s)+CO(g)-1 H3=-36.5kJ molFeO(s)+CO(g)=Fe(s)+CO(g)H4kJ mol-1 SO2(1 2570C570 Cabcd(3CO(a)(b)(C)SFEJOS+CO 4 J|I 400 570 8001200(d)AH 4=N NCH 2CH 2OCH 2CH 2OH HOOC)2 COOH80-60 20-C13H9NO4S 20 FeO(s)+CO(g)Fe(s)+CO2(g)H=-1kJ/mol CO2CO1100CK=0.263CO2)=0.025mol/L,c(CO)=0.1mol/L .A B C COCO2COH2O800 CCO(g)+H2O(g)“CO2(g)+H2(g)K=1.0n(H2O)/n(CO)=1U COCO2 COH2CO+2H 2CH3OH CO+CH3OH T HCOOCH 2 CO80%85%2.52CO1WHI；.I BrjCOOHBiCOOH HBr KMtA(H)NaOH/C2H3OH HOOC SC D i?*COOH S 0 211AB/kJ molI1I2I314A5781817274511578B7381451773310540AB“V”(2KCIMgOCaOTiN4NaCI1MgOMg2Mg23 V2O5CrO24 NNiNaClKClCaO1/kJ mol7867153401 CH3 CH3 1B C 4 A 5 A 6 C 8BD 9 CD 10 D 11 A 12 D 13 D 14 AD H 34NaCIO H3C.C.O N 15 to (MHjOH YOCI mxx 1916(1)Mn2+Fe2+Al3+(2)v；150C Fe2+Fe3+MnO?SO2 NH4HCO35 SO?17acd(NH4)3PO4(NH 4)2HPO4 NH4H2PO4 CO26H+6eCH3OH H2O 224018(1)4.vn(2J cdb(H acd(4)7J(5)57 J%56 0%5%NO2 COOH 19 3 4 5 6 KMnO4BrCH 2CH CHCH 2Br 2NaOH HOCH 2CH CHCH 2OH 2NaBr 201Cu+2Fe3+=2Fe2+Cu2+2 n3=n1+n22 1 CH 3C(=N OH)C(=N OH)CH 3 2 4OH 4e=O2 T+2H2O 2 H2SO4 1 CU2O3.6%2 Fe2O33.2%2 2112 TiN MgO CaOKCl 2 1 0 12 2 CrO2 2 owww.e- sp2 2 A3d74s2 2