最全的标准电极电势优质资料.doc

最全的标准电极电势优质资料(可以直接使用，可编辑 优质资料，欢迎下载）-标准电极电势表-1 在酸性溶液中 (298K) 电对方程式Eq/VLi(I)(0)LieLi3.0401Cs(I)(0)CseCs3.026Rb(I)(0)RbeRb2.98K(I)(0)KeK2.931Ba(II)(0)Ba22eBa2.912Sr(II)(0)Sr22eSr2.89Ca(II)(0)Ca22eCa2.868Na(I)(0)NaeNa2.71La(III)(0)La33eLa2.379Mg(II)(0)Mg22eMg2.372Ce(III)(0)Ce33eCe2.336H(0)(I)H2(g)2e2H2.23Al(III)(0)AlF633eAl6F2.069Th(IV)(0)Th44eTh1.899Be(II)(0)Be22eBe1.847U(III)(0)U33eU1.798Hf(IV)(0)HfO22H4eHfH2O1.724Al(III)(0)Al33eAl1.662Ti(II)(0)Ti22eTi1.630Zr(IV)(0)ZrO24H4eZr2H2O1.553Si(IV)(0)SiF624eSi6F1.24Mn(II)(0)Mn22eMn1.185Cr(II)(0)Cr22eCr0.913Ti(III)(II)Ti3eTi20.9B(III)(0)H3BO33H3eB3H2O0.8698*Ti(IV)(0)TiO24H4eTi2H2O0.86Te(0)(II)Te2H2eH2Te0.793Zn(II)(0)Zn22eZn0.7618Ta(V)(0)Ta2O510H10e2Ta5H2O0.750Cr(III)(0)Cr33eCr0.744Nb(V)(0)Nb2O5l0H10e2Nb5H2O0.644As(0)(III)As3H3eAsH30.608U(IV)(III)U4eU30.607Ga(III)(0)Ga33eGa0.549P(I)(0)H3PO2HeP2H2O0.508P(III)(I)H3PO32H2eH3PO2H2O0.499*C(IV)(III)2CO22H2eH2C2O40.49Fe(II)(0)Fe22eFe0.447Cr(III)(II)Cr3eCr20.407Cd(II)(0)Cd22eCd0.4030Se(0)(II)Se2H2eH2Se(aq)0.399Pb(II)(0)PbI22ePb2I0.365Eu(III)(II)Eu3eEu20.36Pb(II)(0)PbSO42ePbSO420.3588In(III)(0)In33eIn0.3382Tl(I)(0)TleTl0.336Co(II)(0)Co22eCo0.28P(V)(III)H3PO42H2eH3PO3H2O0.276Pb(II)(0)PbCl22ePb2Cl0.2675Ni (II)(0)Ni22eNi0.257V(III)(II)V3eV20.255Ge(IV)(0)H2GeO34H4eGe3H2O0.182Ag(I)(0)AgIeAgI0.15224Sn(II)(0)Sn22eSn0.1375Pb(II)(0)Pb22ePb0.1262*C(IV)(II)CO2(g)2H2eCOH2O0.12P(0)(III)P(white)3H3ePH3(g)0.063Hg(I)(0)Hg2I22e2Hg2I0.0405Fe(III)(0)Fe33eFe0.037H(I)(0)2H2eH20.0000Ag(I)(0)AgBreAgBr0.07133S(II.V)(II)S4O622e2S2O320.08*Ti(IV)(III)TiO22HeTi3H2O0.1S(0)(II)S2H2eH2S(aq)0.142Sn(IV)(II)Sn42eSn20.151Sb(III)(0)Sb2O36H6e2Sb3H2O0.152Cu(II)(I)Cu2eCu0.153Bi(III)(0)BiOCl2H3eBiClH2O0.1583S(VI)(IV)SO424H2eH2SO3H2O0.172Sb(III)(0)SbO2H3eSbH2O0.212Ag(I)(0)AgCleAgCl0.22233As(III)(0)HAsO23H3eAs2H2O0.248Hg(I)(0)Hg2Cl22e2Hg2Cl(饱和KCl)0.26808Bi(III)(0)BiO2H3eBiH2O0.320U(VI)(IV)UO224H2eU42H2O0.327C(IV)(III)2HCNO2H2e(CN)22H2O0.330V(IV)(III)VO22HeV3H2O0.337Cu(II)(0)Cu22eCu0.3419Re(VII)(0)ReO48H7eRe4H2O0.368Ag(I)(0)Ag2CrO42e2AgCrO420.4470S(IV)(0)H2SO34H4eS3H2O0.449Cu(I)(0)CueCu0.521I(0)(I)I22e2I0.5355I(0)(I)I32e3I0.536As(V)(III)H3AsO42H2eHAsO22H2O0.560Sb(V)(III)Sb2O56H4e2SbO3H2O0.581Te(IV)(0)TeO24H4eTe2H2O0.593U(V)(IV)UO24HeU42H2O0.612*Hg(II)(I)2HgCl22eHg2Cl22Cl0.63Pt(IV)(II)PtCl622ePtCl422Cl0.68O(0)(I)O22H2eH2O20.695Pt(II)(0)PtCl422ePt4Cl0.755*Se(IV)(0)H2SeO34H4eSe3H2O0.74Fe(III)(II)Fe3eFe20.771Hg(I)(0)Hg222e2Hg0.7973Ag(I)(0)AgeAg0.7996Os(VIII)(0)OsO48H8eOs4H2O0.8N(V)(IV) 2NO34H2eN2O42H2O 0.803Hg(II)(0)Hg22eHg0.851Si(IV)(0)(quartz)SiO24H4eSi2H2O0.857Cu(II)(I)Cu2IeCuI0.86N(III)(I)2HNO24H4eH2N2O22H2O0.86Hg(II)(I)2Hg22eHg220.920N(V)(III)NO33H2eHNO2H2O0.934Pd(II)(0)Pd22ePd0.951N(V)(II)NO34H3eNO2H2O0.957N(III)(II)HNO2HeNOH2O0.983I(I)(I)HIOH2eIH2O0.987V(V)(IV)VO22HeVO2H2O0.991V(V)(IV)V(OH)42HeVO23H2O 1.00Au(III)(0) AuCl43eAu4Cl1.002Te(VI)(IV)H6TeO62H2eTeO24H2O1.02N(IV)(II)N2O44H4e2NO2H2O1.035N(IV)(III)N2O42H2e2HNO21.065I(V)(I)IO36H6eI3H2O1.085Br(0)(I)Br2(aq)2e2Br1.0873Se(VI)(IV)SeO424H2eH2SeO3H2O1.151Cl(V)(IV)ClO32HeClO2H2O1.152Pt(II)(0)Pt22ePt1.18Cl(VII)(V)ClO42H2eClO3H2O1.189I(V)(0)2IO312H10eI26H2O1.195Cl(V)(III)ClO33H2eHClO2H2O1.214Mn(IV)(II)MnO24H2eMn22H2O1.224O(0)(II)O24H4e2H2O1.229Tl(III)(I)T132eTl1.252Cl(IV)(III)ClO2HeHClO21.277N(III)(I)2HNO24H4eN2O3H2O1.297*Cr(VI)(III)Cr2O7214H6e2Cr37H2O1.33Br(I)(I)HBrOH2eBrH2O1.331Cr(VI)(III)HCrO47H3eCr34H2O1.350Cl(0)(I)Cl2(g)2e2Cl1.35827Cl(VII)(I)ClO48H8eCl4H2O1.389Cl(VII)(0)ClO48H7e1/2Cl24H2O1.39Au(III)(I)Au32eAu1.401Br(V)(I)BrO36H6eBr3H2O1.423I(I)(0)2HIO2H2eI22H2O1.439Cl(V)(I)ClO36H6eCl3H2O1.451Pb(IV)(II)PbO24H2ePb22H2O1.455Cl(V)(0)ClO36H5e1/2Cl23H2O1.47Cl(I)(I)HClOH2eClH2O1.482Br(V)(0)BrO36H5el/2Br23H2O1.482Au(III)(0)Au33eAu1.498Mn(VII)(II)MnO48H5eMn24H2O1.507Mn(III)(II)Mn3eMn21.5415Cl(III)(I)HClO23H4eCl2H2O1.570Br(I)(0)HBrOHel/2Br2(aq)H2O1.574N(II)(I)2NO2H2eN2OH2O1.591I(VII)(V)H5IO6H2eIO33H2O1.601Cl(I)(0)HClOHe1/2Cl2H2O1.611Cl(III)(I)HClO22H2eHClOH2O1.645Ni(IV)(II)NiO24H2eNi22H2O1.678Mn(VII)(IV)MnO44H3eMnO22H2O1.679Pb(IV)(II)PbO2SO424H2ePbSO4+2H2O1.6913Au(I)(0)AueAu1.692Ce(IV)(III)Ce4eCe31.72N(I)(0)N2O2H2eN2H2O1.766O(I)(II)H2O22H2e2H2O1.776Co(III)(II)Co3eCo2(2mol·L1 H2SO4)1.83Ag(II)(I)Ag2eAg1.980S(VII)(VI) S2O822e2SO422.010O(0)(II)O32H2eO2H2O 2.076O(II)(II)F2O2H4eH2O2F2.153Fe(VI)(III)FeO428H3eFe34H2O2.20O(0)(II)O(g)2H2eH2O2.421F(0)(I)F22e2F2.866  F22H2e2HF3.0532 在碱性溶液中 (298K) 电对方程式Eq/VCa(II)(0)Ca(OH)22eCa2OH3.02Ba(II)(0)Ba(OH)22eBa2OH2.99La(III)(0)La(OH)33eLa3OH2.90Sr(II)(0)Sr(OH)2·8H2O2eSr2OH8H2O2.88Mg(II)(0)Mg(OH)22eMg2OH2.690Be(II)(0)Be2O323H2O4e2Be6OH2.63Hf(IV)(0)HfO(OH)2H2O4eHf4OH2.50Zr(IV)(0)H2ZrO3H2O4eZr4OH2.36Al(III)(0)H2AlO3H2O3eAlOH2.33P(I)(0)H2PO2eP2OH1.82B(III)(0)H2BO3H2O3eB4OH1.79P(III)(0)HPO322H2O3eP5OH1.71Si(IV)(0)SiO323H2O4eSi6OH1.697P(III)(I)HPO322H2O2eH2PO23OH1.65Mn(II)(0)Mn(OH)22eMn2OH1.56Cr(III)(0)Cr(OH)33eCr3OH1.48*Zn(II)(0)Zn(CN)422eZn4CN1.26Zn(II)(0)Zn(OH)22eZn2OH1.249Ga(III)(0)H2GaO3H2O2eGa4OH1.219Zn(II)(0)ZnO222H2O2eZn4OH1.215Cr(III)(0)CrO22H2O3eCr4OH1.2Te(0)(I)Te2eTe21.143P(V)(III)PO432H2O2eHPO323OH1.05*Zn(II)(0)Zn(NH3)422eZn4NH31.04*W(VI)(0)WO424H2O6eW8OH1.01*Ge(IV)(0)HGeO32H2O4eGe5OH1.0Sn(IV)(II)Sn(OH)622eHSnO2H2O3OH-0.93S(VI)(IV)SO42H2O2eSO322OH0.93Se(0)(II)Se2eSe20.924Sn(II)(0)HSnO2H2O2eSn3OH0.909P(0)(III)P3H2O3ePH3(g)3OH0.87N(V)(IV)2NO32H2O2eN2O44OH0.85H(I)(0)2H2O2eH22OH0.8277Cd(II)(0)Cd(OH)22eCd(Hg)2OH0.809Co(II)(0)Co(OH)22eCo2OH0.73Ni(II)(0)Ni(OH)22eNi2OH0.72As(V)(III)AsO432H2O2eAsO24OH0.71Ag(I)(0)Ag2S2e2AgS20.691As(III)(0)AsO22H2O3eAs4OH0.68Sb(III)(0)SbO22H2O3eSb4OH0.66*Re(VII)(IV)ReO42H2O3eReO24OH0.59*Sb(V)(III)SbO3H2O2eSbO22OH0.59Re(VII)(0)ReO44H2O7eRe8OH0.584*S(IV)(II)2SO323H2O4eS2O326OH0.58Te(IV)(0)TeO323H2O4eTe6OH0.57Fe(III)(II)Fe(OH)3eFe(OH)2OH0.56S(0)(II)S2eS20.47627Bi(III)(0)Bi2O33H2O6e2Bi6OH0.46N(III)(II)NO2H2OeNO2OH0.46*Co(II)C(0)Co(NH3)622eCo6NH30.422Se(IV)(0)SeO323H2O4eSe6OH0.366Cu(I)(0)Cu2OH2O2e2Cu2OH0.360Tl(I)(0)Tl(OH)eTlOH0.34*Ag(I)(0)Ag(CN)2eAg2CN0.31Cu(II)(0)Cu(OH)22eCu2OH0.222Cr(VI)(III)CrO424H2O3eCr(OH)35OH0.13*Cu(I)(0)Cu(NH3)2eCu2NH30.12O(0)(I)O2H2O2eHO2OH0.076Ag(I)(0)AgCNeAgCN0.017N(V)(III)NO3H2O2eNO22OH0.01Se(VI)(IV)SeO42H2O2eSeO322OH0.05Pd(II)(0)Pd(OH)22ePd2OH0.07S(II,V)(II)S4O622e2S2O320.08Hg(II)(0)HgOH2O2eHg2OH0.0977Co(III)(II)Co(NH3)63eCo(NH3)620.108Pt(II)(0)Pt(OH)22ePt2OH0.14Co(III)(II)Co(OH)3eCo(OH)2OH0.17Pb(IV)(II)PbO2H2O2ePbO2OH0.247I(V)(I)IO33H2O6eI6OH0.26Cl(V)(III)ClO3H2O2eClO22OH0.33Ag(I)(0)Ag2OH2O2e2Ag2OH0.342Fe(III)(II)Fe(CN)63eFe(CN)640.358Cl(VII)(V)ClO4H2O2eClO32OH0.36*Ag(I)(0)Ag(NH3)2eAg2NH30.373O(0)(II)O22H2O4e4OH0.401I(I)(I)IOH2O2eI2OH0.485*Ni(IV)(II)NiO22H2O2eNi(OH)22OH0.490Mn(VII)(VI)MnO4eMnO420.558Mn(VII)(IV)MnO42H2O3eMnO24OH0.595Mn(VI)(IV)MnO422H2O2eMnO24OH0.60Ag(II)(I)2AgOH2O2eAg2O2OH0.607Br(V)(I)BrO33H2O6eBr6OH0.61Cl(V)(I)ClO33H2O6eCl6OH0.62Cl(III)(I)ClO2H2O2eClO2OH0.66I(VII)(V)H3IO622eIO33OH0.7Cl(III)(I)ClO22H2O4eCl4OH0.76Br(I)(I)BrOH2O2eBr2OH0.761Cl(I)(I)ClOH2O2eCl2OH0.841*Cl(IV)(III)ClO2(g)eClO20.95O(0)(II)O3H2O2eO22OH1.24摘自David R.Lide, Handbook of Chemistry and Physics, 825830, 78th. edition, 19971998 * 摘自J.A. Dean Ed,Langes Handbook of Chemistry, 13th. edition, 1985 * 摘自其他参考书. 沾化县富源电化电极壳制造岗位安全操作技术规程（试行） 日期：二零壹零年三月十日目录1适用范围12本岗位概况13管辖范围14本岗位人员要求14.1岗前培训14.2相关培训要求14.3应具备的技能14.4遵章守纪的要求25岗位职责及岗位安全职责25.1岗位职责25.2岗位安全职责26 生产（工艺）原理及术语36.1术语36.2工艺原理37岗位流程37.1流程叙述38 过程(工艺)控制参数49本岗位设备一览表410产品质量指标1011本岗位环境因素识别评价、危险源及风险(见附表)1112生产作业1312.1作业准备1312.2正常操作1313异常情况处理2213.1电动单梁起重机常见故障处理2213.2剪板机异常现象及处理2313.3折弯机异常现象及处理2313.4四柱液压机异常故障及处理2414作业要求2414.1交接班内容2414.2设备维护保养2514.3安全环保要求3014.4安全、环保注意事项3014.5岗位应急措施31电极壳制造岗位安全操作技术规程1适用范围本安全操作技术规程适用于电极壳制造岗位。2本岗位概况本岗位是负责电石炉生产所需电极壳的制造，将外购的方板、圆钢加工成筋板、弧板，并组焊成电极壳。3管辖范围3.1运转设备包括: 一台剪板机、一台开倾压力机、一台折弯机、一台单梁行车、二台四柱液压机、二台点焊机、二台缝焊机。 3.2除此之外还包括电极壳制造车间厂房所属水路系统、气路系统配套管道、阀门、消防器材、工器具及场地、通行道。4本岗位人员要求4.1岗前培训本岗位人员须经安全培训，考试合格后方能上岗操作。特种作业人员必须具有特种作业资格证。4.2相关培训要求新从业人员须经过三级安全教育培训,考试合格后持证上岗。从业人员须掌握本岗位的工艺流程、工艺原理、操作方法，并经考试合格取得操作证。新工艺、技术、装置在投产前必须组织相关人员经培训,考试合格后方可上岗操作。从业人员须积极参加各单位举办的有关法律、法规、厂纪厂规的学习。从业人员必须接受各级单位组织的消防救护、异常情况、特殊情况下的应急处理培训。从业人员每年进行一次安全生产培训教育,考试成绩记入安全作业证和档案。另外以班组为单位每月进行一次安全学习，须有安全员和领导参加，并对学习情况记录、签字。4.3应具备的技能从业人员应具备:基本的化工原理知识和化工操作技能,懂得设备的日常维护保养;对操作中出现的异常情况能作出正确的判断和处理;能正确使用消防救护器材;懂得应急条件的救治、救援方法；掌握安全环保方面的知识。4.4遵章守纪的要求从业人员应作到:遵守国家的法律法规;遵守公司的厂纪、厂规以及车间班组的各种规章制度；杜绝“三违”现象的发生。5岗位职责及岗位安全职责5.1岗位职责（1）、遵守公司、车间的各项规章制度，执行公司调度指令。（2）、熟悉本岗位工艺流程，工艺和质量控制指标，掌握本岗位各项操作技术，了解本岗位各类设备的工作原理及生产中需注意的安全措施。（3）、严格按岗位操作规程操作，坚守岗位，认真执行巡回检查制度，排除设备异常现象，消除事故隐患，自己处理不了的及时报告班长。（4）、为保证供应合格的电极壳，应做好以下工作：A、检查运转设备的运行情况，对存在的问题应及时处理或上报。B、检查公用工程保障情况，特别是水路系统、气路系统各设备、管件完好情况。C、完成每个周期内的设备保养。（5）、按时、齐全、准确、整洁地做好岗位原始记录。（6）、不得提前离开岗位，当班时不得睡觉、打闹、做与生产无关的事情。（7）、管理好本岗位各类工具，保持本岗位清洁卫生。（8）、对违章作业的指示有权拒绝接受，对违章作业者有权加以劝阻，对违章作业的指示和操作有权向各级领导反映。（9）、积极配合、参与公司、车间各项活动。（10）、完成公司、车间交给的其它任务。5.2岗位安全职责（1）岗位操作人员必须严格按照操作规程、工艺规程进行操作，禁止违章操作和冒险蛮干。（2）岗位操作人员有权拒绝使用不安全的工具、设备，有权拒绝违章指挥。（3）进入岗位前，必须按规定佩带齐全本岗规定的劳动防护用品用具。（4）应经常保持各岗位环境的整洁和工作通道的畅通，不准在岗位上堆放与生产无关的物品。（5）电极壳制造过程中要注意防止机械伤害、焊接点高温伤害。（6）焊接前检查循环水池盖密封情况，设备接地情况，防止溺水、触电伤害。6 生产（工艺）原理及术语6.1术语电阻焊：焊件组合后通过电极施加压力，利用电流通过接头的接触面及邻近区域产生的电阻热进行焊接的方法称为电阻焊。本岗位交流缝焊机、悬挂式点焊机均是电阻焊机。电极壳：自焙电极使用的钢套，内有铁翅和拉筋，用以增加电极的强度和导电性，电极壳安装在电极把持器内，通过点击夹紧装置延伸到电石炉中反应区。本岗位设计电极壳直径1250mm，长度1500mm，使用弧板、筋板组焊而成。6.2工艺原理本岗位主要是通过弧板、筋板加工制作，组合焊接成电极壳。7岗位流程7.1流程叙述弧板制作：将=2mm方板经液压剪板机剪切成尺寸为1500X374的方板，通过四柱液压机弧板压制模具压制成弧板。筋板制作：将=3mm方板经液压剪板机剪切成尺寸为1500X283、445X230的方板，通过开倾压力机冲孔模具冲孔，然后使用板料折弯机将大小筋板折弯。大筋板、小筋板、圆钢焊接成筋板。焊接电极壳：在电极壳组焊小车上，分别插上弧板、筋板、弧板，使用组对夹具箍紧，先使用点焊机对弧板、筋板进行点焊，完成电极壳组装，再使用缝焊机对电极壳缝焊，完成焊接后使用角磨机对焊接处磨光。8 过程(工艺)控制参数大筋板尺寸：1500X283小筋板尺寸：445X230弧板尺寸：1500X3749本岗位设备一览表电极壳制造车间设备一览表位号名称数量型号/参数用途X1101液压剪板机1台描述见下钢板剪板X1102开倾压力机1台描述见下X1103工作台3架非标剪板机剪板台、开倾压力机冲孔台、焊接翻转架X1104液压摆式折弯机1台描述见下筋板、弧板折弯X1105手工交流弧焊机2台20.5KVA,负载持续率60%筋板焊接X1108滚动焊接架2台非标电极壳组焊X1109缝焊机2台FN-400-1电极壳缝焊X1111悬挂点焊机2台DN-160-1电极壳点焊X1112手摇滚动架2台非标电极壳组焊X1113空压机1台0.6m3/min，1.0MPa焊机气路系统X1114角磨机4台GWS8-100电极壳磨光X1115四柱液压机2台描述见下平板、弧板压制L1101电动单梁起重机1台描述见下电极壳吊运P1101水泵1台扬程26m，流量3.8m3/h焊机水路系统LDA型单粱起重机LDA型单粱起重机用途为电极壳制造厂房内的电极壳吊运，主要性能参数如下：1）起重量Q=3t2）起升高度H=8m 3）跨度13.5m4）轮压 2.64KN5）电机功率起升主电机4.5Kw小车运行0.4Kw大车运行0.8Kw×2电动葫芦重量297kg 整机重量2650kg 6）钢丝绳绳直径 13mm绳总长 22m结构型式W6×37+17）防护等级IP548）运行距离60m9）吊钩类型锻造单钩10) 轨道型号P2411) 速度起升主8m/min小车运行20m/min大车运行30m/min频率50Hz12）工作制度A513）操作方式地面式14）绝缘等级F级YL32-315型四柱液压机YL32-315型四柱压力机基本性能参数序 号项 目规 格单 位备注1公称力3150KN2顶出力630KN3回程力600KN4滑块行程800mm5顶出行程300mm6最大开口高度1250mm7滑块速度空 程100mm/s工 作512mm/s回 程60mm/s8顶出速度上 升55mm/s退 回145mm/s9工作台有效尺寸左 右1260mm前 后1160mm10机器外形尺寸左 右3500mm前 后1500mm地面上高度4600mm11电机功率22KW12整机重量14000KgWC67Y-63/2500液压摆式折弯机WC67Y-63/2500液压摆式折弯机性能参数型号名 称规 格单位备 注1公称力630KN2工作台长度2500mm3滑块空载行程次数10min4立柱间距离2000mm5喉口深度250mm6滑块行程100mm7工作台面与滑块间最大开启高度340mm8滑块行程调节量80mm9液压系统工作压力20MPa10滑块行程速度空 载50mm/s满 载12mm/s回 程40mm/s 11内啮合齿轮泵型 号NT2-G12F系统最大工作压力为20MPa流 量12L/min压 力32MPa12主电机型 号Y132S-4 B35功 率5.5kW转 速1440r/min13滑块行程调节电机型 号YS711-6功 率180W转 速910r/min14后挡料电机型 号Y802-M-6-B3功 率0.55KW转 速910r/min15外形尺寸长2800mm宽1480mm高2180mm16机床质量4250KgQC12Y-6×2500液压剪板机QC12Y-6×2500液压剪板机性能参数序 号名 称数 值单 位备 注1可剪最大板厚6mm被 剪 板 强 度450N/mm22