2022年热力学函数 .pdf

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1、298.15K 和 100kPa 时一些单质和化合物的热力学函数单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ)g(O249.170 231.731 161.055 21.912 )g(O20 0 205.138 29.355 )g(O3142.7 163.2 238.93 39.2 )g(H217.965 203.247 114.713 20.784 )g(H20 0 130.684 28.824 )g(OH2- 241.818 - 228.572 188.82533.577 ) l (OH2-285.830-237.12939.91 75.291

2、) l (OH22-187.78-120.35109.6 89.1 第 0 族)g(He0 0 126.150 20.786 )g(Ne0 0 146.328 20.786 )g(Ar0 0 154.843 20.786 )g(Kr0 0 164.082 20.786 )g(Xe0 0 169.683 20.786 )g(Rn0 0 176.21 20.786 第族)g(F20 0 202.78 31.30 )g(HF-271.1-273.2173.779 29.133 )g(Cl20 0 223.066 33.907 )g(HCl-92.307-95.299186.908 29.12 名师资

3、料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 1 页，共 8 页 - - - - - - - - - 298.15K 和 100kPa 时一些单质和化合物的热力学函数续 表单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ)g(Br230.907 3.110 245.463 36.02 ) l (Br20 0 152.231 75.689 )g(HBr-36.23-53.22198.24 29.12 )g(I262.438 19.327 260.69

4、 36.90 )cr(I20 0 116.135 54.438 )g(HI26.48 1.70 206.594 29.158 第族),cr(S正交晶体0 0 31.80 22.64 ),cr(S单斜晶体0.33 -)g(SO2-296.830-300.194248.22 39.87 )g(SO3-395.72-371.06256.76 50.67 )g(SH2-20.63-33.56205.79 34.23 第族)g(N20 0 191.61 29.125 )g(NO90.25 86.55 210.761 29.844 )g(NO233.18 51.31 240.06 37.20 )g(ON2

5、82.05 104.20 219.85 38.45 )g(ON429.16 97.89 304.29 77.28 )cr(ON52-43.1113.9 178.2 143.1 )g(NH3-46.11-16.45192.45 35.06 名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 2 页，共 8 页 - - - - - - - - - 续 表单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ) l (HNO3-174.10-80.71155.

6、60 109.87 )cr(ClNH4-314.43-202.8794.6 84.1 ),cr(P白色0 0 41.09 23.840 ),cr(P三斜晶体红色-17.6-12.122.80 21.21 )g(P458.91 24.44 279.98 67.15 ),cr(OP104六方晶体-2984.0-2697.7228.86 211.71 )g(PH35.4 13.4 210.23 37.11 第族),cr(C石墨0 0 5.740 8.527 ),cr(C金刚石1.895 2.900 2.377 6.113 )g(C716.682 671.257 158.096 20.838 )g(C

7、O-110.525-137.168197.674 29.142 )g(CO2-393.509-394.359213.74 37.11 )g(CH4-74.81-50.72186.264 35.309 )g(ClCH3-80.83-57.37234.58 40.75 )g(CHCl3-103.14-70.34295.71 65.69 ) l (CHCl3-134.47-73.66201.7 113.8 )g(CCl4-102.9-60.59309.85 83.30 ) l (CCl4-135.44-65.21216.40 131.75 )g(BrCH3-35.1-25.9246.38 42.43

8、 名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 3 页，共 8 页 - - - - - - - - - 298.15K 和 100kPa 时一些单质和化合物的热力学函数续 表单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ) l (CS289.70 65 151.34 75.7 )g(HCN135.1 124.7 201.78 35.86 )g(OHCH3-200.66-161.96239.81 43.89 ) l (OHCH3-238.66

9、-166.27126.8 81.6 ) l (HCOOH-424.72-361.35128.95 99.04 )g(CHOCH3-166.19-128.86250.3 57.3 )cr()NH(CO22-333.51-197.33104.60 93.14 )g(HC6682.9 129.7 269.2 82.4 ) l (HC6649.1 124.5 173.4 136.0 )cr(Si0 0 18.83 20.00 ),cr(SiO2石英-910.94-856.6441.84 44.43 )cr(Pb0 0 64.81 26.44 第族)cr(B0 0 5.86 11.09 )cr(OB32

10、-1272.77-1193.6553.97 62.93 )g(HB6235.6 86.7 232.11 56.90 )g(HB9573.2 175.0 275.92 96.78 )cr(Al0 0 28.33 24.35 ),cr,(OAl32刚玉-1675.7-1582.350.92 79.04 第B族名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 4 页，共 8 页 - - - - - - - - - 298.15K 和 100kPa 时一些单质和化合物的热力学函数续 表单质或化

11、合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ)cr(Zn0 0 41.63 25.40 )cr,(ZnS纤锌矿-192.63-)cr,(ZnS闪锌矿-205.98-201.2957.7 46.0 ) l (Hg0 0 76.02 27.983 ),cr(HgO红色，斜方晶体-90.83-58.53970.29 44.06 ),cr(HgO黄色-90.46-58.40971.1 )cr(HgCl2-224.3-178.6146 )cr(ClHg22-265.22-210.745192.5 第 B族)cr(Cu0 0 33.150 24.435 )cr(OCu2

12、)cr(CuO- 157.3 -129.742.63 42.30 )cr(CuSO4-771.36-661.8109 100.0 )cr(O5HCuSO24-2279.65-1879.745300.4 280 )cr(Ag0 0 42.55 25.351 )cr(OAg2-31.05-11.20121.3 65.86 )cr(AgCl-127.068-109.78996.2 50.79 )cr(AgNO3-124.39-33.41140.92 93.05 第 B族)cr(Fe0 0 27.28 25.10 名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - -

13、 - - - - - - 名师精心整理 - - - - - - - 第 5 页，共 8 页 - - - - - - - - - 298.15K 和 100kPa 时一些单质和化合物的热力学函数续 表单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ)cr,(OFe43磁铁矿-1118.4-1015.4146.4 143.43 )cr,(OFe32赤铁矿-824.4-742.287.40 103.85 第B族)cr(Mn0 0 32.01 26.32 )cr(MnO2-520.03-465.1453.05 54.14 第B族)cr(T i0 0 30.29

14、25.15 )cr(TiO2-912-852.750.25 55.06 ) l (T iCl4-750.2-252.7 第 族)cr(Be0 0 9.50 16.44 )cr(Mg0 0 32.68 24.89 )cr,(MgO方镁石-601.70-569.4326.94 37.15 )cr()OH(Mg2-924.54-833.5163.18 77.03 )cr(MgCl2-641.32-591.7989.62 71.38 )cr(Ca0 0 41.42 25.31 )cr(CaO-635.09-604.0339.75 42.80 )cr(CaF2-1219.6-1167.368.67 67

15、.03 )cr,(CaSO4无水石膏-1434.11-1321.79106.7 99.66 )cr,(OH21CaSO24-1576.74-1436.74130.5 119.41 名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 6 页，共 8 页 - - - - - - - - - 298.15K 和 100kPa 时一些单质和化合物的热力学函数续 表单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ)cr,(O2HCaSO24透石膏-2022.

16、63-1797.28194.1 186.02 ),cr,()(POCa243低温形-4120.8-3884.7236.0 227.82 )cr,(CaCO3方解石-1206.92-1128.7992.9 81.88 )cr,(SiOCaO2钙硅石-1634.94-1549.6681.92 85.27 第族)g(Li159.37 126.66 138.77 20.786 )g(Li2215.9 174.4 196.996 36.104 )cr(Li0 0 29.12 24.77 )cr(OLi2-597.94-561.1837.57 54.10 )g(LiH139.24 116.47 170.9

17、00 29.727 )cr(LiCl-408.61-384.3759.33 47.99 )g(Na107.32 76.761 153.712 20.786 )g(Na2142.05 103.94 230.23 37.57 )cr(Na0 0 51.21 28.24 )cr(NaO2-260.2-218.4115.9 72.13 )cr(ONa2-414.22-375.4675.06 69.12 )cr(ONa22-510.87-447.795.0 89.24 )cr(NaOH-425.609-379.49464.455 59.54 )cr(NaCl-411.153-384.13872.13 5

18、0.50 名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 7 页，共 8 页 - - - - - - - - - 298.15K 和 100kPa 时一些单质和化合物的热力学函数续 表单质或化合物mfH1molkJmfG1molkJmS11KmolJmp,C11KmolJ)cr(NaBr-361.062-348.98386.82 51.38 )cr,(SONa42斜方晶体-1387.08-1270.16149.58 128.20 )cr(O10HSONa242-4327.26-364

19、6.85592.0 -)cr(NaNO3-467.85-367.00116.52 92.88 )cr(CONa32-1130.68-1044.44134.98 112.30 )g(K89.24 60.59 160.336 20.786 )g(K2123.7 87.5 249.73 37.89 )cr(K0 0 64.18 29.58 )cr(OK2-361.5-)cr(KOH-424.764-379.0878.9 64.9 )cr(KCl-436.747-409.1482.59 51.30 )cr(KMnO4-837.2-737.6171.71 117.57 名师资料总结 - - -精品资料欢迎下载 - - - - - - - - - - - - - - - - - - 名师精心整理 - - - - - - - 第 8 页，共 8 页 - - - - - - - - -