有机物换算成COD表05984(37页).doc

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1、-有机物换算成COD表05984-第 2 页表1 常见化合物的CODCr、CODMn、BOD5、TOD和TOC之相关值（1） 烃及卤代烃类序号化合物名称结构式化合物浓度（mg）THODCODcrCODcrTHOD (%)CODcrCODcrTHOD (%)BOD5BOD5THOD (%)TODTODTHOD (%)THODTOCTOC THOC(%)BOD5CODcrTHOD THOC1甲烷CH4100040007502一氯甲烷CH3Cl10009504772872383二氯甲烷CH2Cl21000376(360)014124三氯甲烷CHCl310005363351005(101)5三溴甲烷C

2、HBr31000(253)0(48)6四氯化碳CCl41000(416)208078(78)7乙烷CH3CH310003725798818环氧乙烷CH2CH2O10001877(2210)11702005459二氯乙烷C2H4Cl210001132(810)2425(243)101、2二氯乙烷ClCH2CH2Cl1000(258)113254519824318511三氯烷Cl2CHCH2Cl1000840(180)12四氯乙烷Cl2CHCHCl21000(201)667496242143(143)22313丙烷H3CCH2CH31000362981714环氧丙烷CH2CHCH3O1000220

3、3(2210)62015CH2CHCH2Cl Cl1000(182）113248024734919716CH2CHCH2Cl Br Br1000425(440)15317CH2=C-CH=H3C10003294(3240)425(440)88218CF3CH2ClCH21000727(350)27319正十二烷C12H2010003482(3480)28084720汽油7821石油1000(35004500)3000430030043022重油3000366033023煤油53024乙烯H2C=CH21000342985725Cl2C=CH21000667990250（2） 醇类化合物序号化合

4、物名称结构式化合物浓度（mg）THODCODcrCODcTHOD (%)rCODmnCODmn THOD (%)rBOD5BOD5THOD (%)rTODTODTHOD (%)rTHOCTOCTOC THOC(%)rBOD5COD5THOD THOCTHON1甲醇CH3OH100010050150075142014409040027102011208875513853739981032乙醇C2H3OH1000100502080198010902301111.0751570100072239523苯甲醇C6H5CH2OH100025154817304氯乙醇ClCH2CH2OH1000993298

5、5氰乙醇NCCH2CH2OH100013508001976氨基乙醇NH2CH2CH2OH100013101200(198.3)930(132.2)343563937乙酰氨基乙醇CH2CH2OHNH2COCH31000140011008甲氧基乙醇CH2CH2OHOCH310001682（1680）110065547313569乙氧基乙醇CH2CH2OHOC2H610001953(1960)106010苯乙醇C6H5CH2CHOH21000(2620)1500158011正丙醇C3H2OH10001002396(2400)24022202240310154015802335994412异丙醇CH3

6、CHOHCH310002396(2400)22402250(349.8)64(26.3)1590392599133.氯丙醇CH2CH2CH2OHCl10001354(1350)1360141,3二氯丙醇CH2CH2CHOHCl Cl1000868(1200)84011601015丙烯醇CH2=CHCH2OH10002203(2216)1682420179016216丁醇C4H9OH10002590(2600)240024102801140126017异丁醇CH3CHCH2OHCH3/10002590(2600)229923002401600166018特丁醇C4H9OH10002590(260

7、0)2180(282.9)848400032519戊醇C5H11 OH10002723(2730)1230162020异戊醇CH3CHCH2OHCH3/10002723(2730)150020异戊醇50136(120)7663100343521己 醇C6H16OH10002819(2820)22环己醇C6H6OH10002819(2820)160023(2)CH3CHCH2CHCH8CH3/ OH10002829(2820)24辛醇C5H17OH10002949(2950)全120073725异壬醇C9H10OH10002995(3000)28009374926乙二醇CH2OHCH2OH100

8、0100501289(1290)1240(221.5)100490(66.9)5038829221625387390. 427聚乙二醇（CHCHOHOH）n10003003028丙二醇(1,2)CH2CHCH3OH OH10001682(1690)1630116047329丙二醇(1,3)CH2CH2CHOH OH10001682(1680)1640全27647330甲基,丁二醇(1,3)CH3C CH2CH2OHCH3 OH10002151(2140)全1350576311,氯丙二醇(1,2)ClCHCHCH3 OH OH10001017(920)327322,甲基戊二醇(2,4)CH3CC

9、H2CHCH3CH3/ OH OH10002302(2301)6532960933丙三醇CH2 CH CH2 OH OH OH1000100601216(1200)221.510011701180(282.8)95366301952810770284203103513910434季戊四醇C(CH2OH)410001410(1420)6035ClCH2 /CH2OHCClCH2/ CH2OH100036聚乙烯醇(CH2=CHOC)nn=175018183037正十二烷醇10003040460（3） 醚类化合物 化合物名称化合物浓度（mg）THODCODCrCODCr/THOD (%)CODMnC

10、ODMn/THOD (%)BOD5BOD5/THOD (%)TODTOD/THOD (%)THODTOCTOC /THOC(%)BOD5/CODcrTHOD THOC1乙醚C2H5OC2H510002595(2590)827849(136.7)100343(647.6)2O(C2H4OH)21000100091060全1763O(C2H4OC2H5)210002173(2180)1004苯甲醚C5H6OCH310002516170777（4） 醛类化合物序号化合物名称结 构 式化合物浓度（mg）THODCODcrCODcrTHOD (%)CODmnCODmnTHOD (%)BOD5BOD5TH

11、OD (%)TODTODTHOD (%)THOCTOCTOC THOC(%)BOD5CODcrTHOD THOC1甲醛HCHO10001005010704998137619046073560680264004020361890900.842苯甲醛C6H5CHO10002412(2420)287198080801500 16206767533二甲氧基缩甲醛CH(OCH3)210001620(1680)16402702704804乙醛CH3CHO10001618(1820)82010501501906509103685丙醛C2H5CHO10002204(2200)全11906丙烯醛CH=CHCHO

12、10001998(2000)17208066033642(643)7苯基丙烯醛C6H5CH2=CHCHO10002523(2559)8丁醛C3H7CHO10002441(2440)11609丁烯醛CH3CH=CHCHO10002280(2410)800103羟基丁醛H3CCHCH2CHOOH10001820(1750)11糠醛- CHOO10001665(1670)77012苯甲醛C6H5CHO10002412(2420)2871980(229.6)801500162062.2677925813三氯乙醛Cl3CCHO1000220162.814二甲氧缩甲醛OCH3CHOCH310001620(

13、1680)16402704863.33（5） 酮类化合物序号化合物名称结 构 式化合物浓度（mg）THODCODcrCODcrTHOD (%)CODmnCODmnTHOD (%)BOD5BOD5THOD (%)TODTODTHOD (%)THODTOCTOC THOC(%)BOD5CODcrTHOD THOC1丙酮CH3COCH310001002204(2210)2201102218802707(149.4)8594848101120(66)3737215103989462040770.540.442甲乙酮CHCOC2H5100010050244019202200(286)90771810(2

14、74.9)7474891046065903甲基异丙基酮H3CCOCH(CH3)210002002672674环乙酮C6H6O26122610)10005甲基异丁基酮CH3COCH2CH(CH3)2100027122720）120471933786甲基戊基酮CH3COC5H1110002805（2800）7氧甲基吡咯烷酮N =OCH38苯乙酮C6H5COCH3表2 工业中常见有机化合物的一些有关参数序号化合物名称熔点沸点密度kg/L水中溶解度g/L动物半死量LDmg/kgCOD值g/gBOD值g/g生物可降解性毒性mg/L1一乙胺易0.375+292一甲胺易+3一氯乙酸61189易1650.51

15、+4一氯甲烷-97.7-245005乙二胺117互溶11600.01(1.0)0.008+6乙二醇-13198互溶85401.150.67(0.91)0.84+100007乙二醇单乙醚135互溶3000(致死量)0.806+8乙二醇单丁醚-401709乙二醇单甲醚-85124互溶3400(致死量)0.120.50(1.10)1000010乙苯-953500+1211乙苯胺（混合物）0.127+12乙炔-8400-132-乙基已醇-7611060(-2.29)0.78+8214乙基仲戊基酮1601622515乙烯亚胺-715556互溶16乙脯互溶6120.898+68017乙酰乙酸乙酯18018

16、118乙酰丙酮1391250.1(1.24)6719乙酰马啉141526130020乙酰苯汞153100021乙酰苯胺1143054001.222乙酰胺222易300000.583+1000023乙酸互溶33000.805+24乙酸乙烯酯-100732516130.597+625乙酸乙酯800.86(1.57)0.80+26乙酸丁酯1432000.236+11527乙酸丙酯-9510217028乙酸戊酯-751480.132+14535029乙酸异丁酯1180.67(2.05)0.932+20030乙酸异丙酯-7390180.129+19031乙酸环已酯17718332乙酸苯酯19611533

17、乙酸叔丁酯967834乙酸钙42800.592+35乙酸钠1230.75+36乙酸钾25532500.50+37乙酸铵易38乙醇-117互溶65000.875+650039乙醇胺11172互溶6500.780.93(1.88)0.61+630040乙醛-124互溶19300.91(1.07)0.59+41乙醛酸7942乙醚-116356943二乙汞440044二乙铵-45互溶6480.445+45N,N-二乙基苯胺2160046N,N-二乙基羟胺47二乙烯三胺五醋酸48二乙醇胺28269互溶1200.095+1000049二丙酮醇-57169400082550二甘醇单乙醚202互溶859097

18、4025551二甘醇单丁酯-68231互溶52二甘醇单丁醚-68231互溶5500660053二甲苯0.309+54二甲苯胺（混合物）0055二甲氧基甲烷4433056二甲胺易2401.3(0.4)0.653+572,5二甲基-1,4二恶烷200582,4-二甲酚260592,5-二甲酚732120602,6二甲酚4620357600.313,+613,4二甲酚65225623,5二甲酚6821963二异丙胺50064二异丙醚-8669950006500（致死量）65二苯醚282593990662,6二叔丁基-4-甲基酚70265180067N,N二甲基甲酰胺-61153互溶42000.02(

19、0.10)0.065,683,3-二甲基戊二酸1020.02,1.47)69二甲基亚砜18970N,N-二甲基苯胺219210.250.095,712,4-二甲基苯胺2188722,5-二甲基苯胺2170734,4二氨基二苯甲烷93231/1115742,6-二氨基吡啶12128500752,6-二羟基异菸酸3000.086,(0.10)762,4-二硝基甲苯703000057772,6-二硝基甲苯646626782,4-二硝基苯酚1143011579二硫化碳35(N)80二硫代磷酸-0,0-二甲酯2510000811,1-二氯乙烷135821,2-二氯乙烷625,6800083二氯乙酸619

20、44500842,2-二氯二乙醚-501781120851,4-二氯-2-丁烯丁基158861,3-二氯-2-丙醇1101000872,2-二氯丙酸钠500470088二氯甲烷13160000892,4-二氯苯氧乙酸2160.5720902,4-二氯苯酚452106912,3-二氯-1,4-萘醌18844000921,4-二恶烷10101互溶566000270093十六烷828794十氢萘（顺）-431940095十氢萘（反）-3118600961,3-丁二烯-10097丁二腈8026712845098丁二酸18523568991,4-丁二醇16230互溶100丁苯-881830.49,(1.

21、96)0.153,101丁胺互溶4308001022-丁烯醛-74180 0.8(2.12)1032-丁酮370401150104丁酮肟152100105丁酸5629003800875106丁酸乙酯124127141401071-丁醇-871603650,8200(N)1082-丁醇1256480500109丁醛-977537100110三乙胺435111三乙醇胺360互溶220010000112三甘氨酸24411002400113三甘醇-4互溶2260320114三甘单乙醚2601151,3,5-三甲苯116三甲胺-117590(N)1172,2,4-三甲基戊烷1010.00561181,1,1-三氟-3-氯丙烷001193,4,5三羟基苯甲酸220500120三硝基甲苯81240爆炸100121三硝基甲烷25122三硝基酚300爆炸001231,1,2-三氯乙烷354.593124三氯乙烯-8765125三氯乙酸57131001261,2,4-三氯苯1721310001272,4,5-三氯苯氧乙酸158500(-0.17)128己二胺4219613000.03,(1.58)129己二腈2951000130己二酸15315131己二酸已二胺盐1905001610132己二酸钠133己内酰胺-2134己烷1352-己酮-5712835136