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(完整版)高分子化学试题合辑附答案.pdf

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1、高分子化学课程试题一、基本概念（共15 分,每小题 3 分）动力学链长引发剂半衰期二、填空题（将正确的答案填在下列各题的横线处）(每空 1 分，总计20 分)自由聚合的方法有本体聚合、溶液聚合、乳液聚合和悬浮聚合。逐步聚合的方法有熔融缩聚、溶液缩聚、固相缩聚和界面缩聚。聚氨酯大分子中有、和基团。聚合反应按反应机理可分为连锁聚合、逐步聚合、开环聚合和聚合物之间的化学反应四类。聚合物按大分子主链的化学组成碳链聚合物、杂链聚合物、元素无机聚合物和元素有机聚合物四类。三、简答题（共 20 分，每小题 5 分）乳液聚合的特点是什么?什么叫自由基？自由基有几种类型？写出氯乙烯自由基聚合时链终止反应

2、方程式。四、（共 5 分，每题 1 分）选择正确答案填入()中。自由基共聚合可得到(1 4)共聚物。得分得分无规共聚物嵌段共聚物接技共聚物交替共聚物为了得到立构规整的PP，丙烯可采用(4)聚合。自由基聚合阴离子聚合阳离子聚合配位聚合工业上为了合成聚碳酸酯可采用(1 2)聚合方法。熔融缩聚界面缩聚溶液缩聚固相缩聚聚合度基本不变的化学反应是(1)PVAc 的醇解聚氨酯的扩链反应高抗冲PS 的制备环氧树脂的固化表征引发剂活性的参数是(2 4)kp(t1/2kikd五、计算题（共 35 分，根据题目要求计算下列各题）(15 分)用过氧化二苯甲酰(BPO)作引发剂，60

3、研究甲基丙烯酸甲酯的本体聚合。已知：C(偶合终止系数)0.15；D(歧化终止系数)0.85；f 0.8；kp 3.67 102 L/mol.s；kd 2.0 10-6 s-1；kt9.30 106 L/mol.s；c(I)0.01 mol/L；CM1.85 10-5；CI 2 10-2；甲基丙烯酸甲酯的密度为0.937 g./cm3；计算：聚甲基丙烯酸甲酯(PMMA)的平均聚合度nX。高分子化学课程试题一、基本概念（共14 分，5.2 分,其余 3 分）自由基共聚合反应文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D

4、4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V

5、10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK1

6、0D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M

7、9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编

8、码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H

9、5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O

10、2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5 引发剂二、填空题（将正确的答案填在下列各题的横线处）(每空 1 分，总计 20 分)自由聚合的单体有、和等。单体可分为、和三大类。表征乳化剂性能的指标是、和。阴离子聚合的引发体系有强碱、碱金属和碱金属配合物。某些聚合物按大分子主链中含的特征基团可命名为聚酯、聚酰胺、和聚醚聚合物等。根据共聚物

11、大分子链中单体单元的排列顺序，共聚物分交替共聚物、无规共聚物、嵌段共聚物、接枝共聚物四类。三、简答题（共 20 分，每题 5 分）什么叫聚合物相对分子质量的多分散性？何谓自动加速现象？并解释产生的原因。高分子化学课程试题一、基本概念（共10 分,每小题 2 分）阴离子聚合平均聚合度阻聚剂得分得分文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4

12、R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10

13、ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5

14、B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5

15、文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:C

16、W3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4

17、U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 H

18、Y1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5二、填空题（将正确的答案填在下列各题的横线处）(每空 1 分，总计20 分)连锁聚合包括自由基聚合、阴离子聚合、阳离子聚合和配位阴离子聚合。连锁聚合的全过程一般有链引发、链增长、链转移和链终止等几个基元反应。环状类单体主要有、和等几类。控制共聚物组成的方法有、和等方法。聚合物的化学反应按反应前后聚合度的变化情况可分、和等化学反应。缩聚物按大分子形态可分为线性缩聚物和体型缩聚物两类。三、简答题（共20 分，每小题 5 分）乳液聚合动力学的特点是什么?高分子化学课程试

19、题一、基本概念（共10 分,每小题 2 分）得分文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4

20、R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10

21、ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5

22、B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5

23、文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:C

24、W3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4

25、U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5 混缩聚2聚合物3.重复单元4阳离子聚合5悬浮剂二、填充题（将正确的答案填在下列各题的横线处,每空 1 分，总计20 分

26、）在自由基聚合体系中,用引发剂引发的引发速率方程式。2塑料按其受热行为的不同可分为热塑性塑料和热固性塑料。3在合成聚合物中合成纤维、合成橡胶和塑料称为三大合成材料。4表征聚合物相对分子质量的物理量有平均聚合度和动力学链长。5按自由基和阴离子聚合的单体有、和等。6聚氨酯可以看成是由和构成的嵌段共聚物。7逐步聚合包括缩聚和逐步加成聚合两类。8.聚合物的相对分子质量方面的特征是巨大、具有多分散性、用平均相对分子质量表示。9氯乙烯自由聚合时，聚合速率用调节，而聚合物的相对分子质量用控制。三、回答问题(共 20 分,每小题 5 分)阴离子聚合在适当的条件下，其阴离子活性增长链可以长期不终止，而形成活性聚

27、合物，为什么？与低分子化合物相比较，高分子化合物有哪些特点？相对分子质量（大具有多分散性用平均相对分子质量表示）具有一二三四级结构得分得分文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D

28、4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V

29、10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK1

30、0D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M

31、9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编

32、码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H

33、5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5聚集态（只有液固无气态）高分子

34、化学课程试题一、基本概念（共10 分,每小题 2 分）链增长反应.相对分子质量分布曲线向单体转移常数MC 本体聚合三、填充题（根据题意，在下列各题的横线处，填上正确的答案，本大题共6 小题，每空 1 分，总计 20 分）.按橡胶的成本、产量和性能可将其分为橡胶和橡胶。引发剂引发的自由基聚合体系中，影响聚合速率的因素是单体浓度、引发剂浓度、温度和引发剂分解活化能。阴离子聚合体系中活性中心离子对可能以、和等三种形态存在。烯类单体自由基聚合时,终止方式与和有关，最后由决定。线型缩聚的单体有、和等。得分文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW

35、3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U

36、9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY

37、1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R

38、6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 Z

39、K10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B

40、8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文

41、档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5 聚合物的平均聚合度变大的化学反应有嵌段、接枝和等。四、简答题（共 3 小题，共 20 分）高分子化学课程试题一、基本概念（共10 分,每小题 2 分）本体聚合引发剂的诱导分解二、填空题（共 20 分,每空 1 分）体型缩聚物有、和等。线型缩聚物有、和等。计算体型

42、缩聚的凝胶点有方程和统计公式。引发剂的选择原则是根据聚合实施方法选择引发剂的种类、根据聚合温度选择引发剂的分解活化能适当的引发剂、根据聚合周期选择引发剂的半衰期适当的引发剂。本体聚合应选择油溶性引发剂、乳液聚合应选择水溶性引发剂。得分得分得分文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J

43、4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2

44、HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G

45、4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10

46、 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D

47、5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J

48、5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:

49、CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5三、简答题（共 25 分,每题 5 分,意义不完全者适当扣分）界面缩聚的特点是什么?四、（共 5 分，每题 1 分）选择正确答案填入()中。接技共聚物可采用（）聚合方法。逐步聚合反应聚合物的化学反应阳离子聚合阴离子聚合为了得到立构规整的1.4-聚丁二烯，1,3 丁二烯可采用()聚合。自由基聚合阴离子聚合阳离子聚合配位聚合工业上为了合成涤纶树脂(PET)可采用()聚合方法。熔融缩聚界面缩聚溶液缩聚固相缩聚聚合度变大的化学反应是()PVAc 的醇解纤维素硝化高抗冲 PS 的制备离子交换树脂的制备

50、表征聚合物相对分子质量的参数是(、)1rt1/2nX高分子化学课程试题一、基本概念（共15 分,每小题 3 分）聚合物的无规热降解缩合反应和缩聚反应共聚合和共聚物文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW3H5J4U9O2 HY1D4G4R6V10 ZK10D5B8M9J5文档编码:CW

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