书签分享收藏举报版权申诉 / 7

立即下载

当前位置：首页 > 教育专区 > 高考资料 > 2021年有机化学第三学期模拟试题及答案.pdf

2021年有机化学第三学期模拟试题及答案.pdf

上传人：Q****o

文档编号：56619007

上传时间：2022-11-02

格式：PDF

页数：7

大小：206.54KB

( 4.5 )

《2021年有机化学第三学期模拟试题及答案.pdf》由会员分享，可在线阅读，更多相关《2021年有机化学第三学期模拟试题及答案.pdf（7页珍藏版）》请在淘文阁 - 分享文档赚钱的网站上搜索。

1、台州学院化学专业有机化学第三学期模拟试题（1）题号一二三四五六七总分分值8 15 21 12 25 10 9 100 得分一、用系统命名法命名下列化合物或写出相应的结构式(8 分)（共 8 题，每题 1 分）1.苦味酸2.（S,3R）-3-溴环己醇1.OHNO2NO2O2N 2.OHHBrH3(2Z)-4,4-二甲基-3-乙基-2-溴-2-戊烯4.(2S,3R)-2-氯-3-溴丁烷5.2-(3-羟基苯基)-1-丙醇6.乙烯基乙基醚3.BrCCCH3CH2CH3C(CH3)34.H3CHClCH3HBr5.CHCH2OHOHCH36.CH3CH2OCH=CH27.n-Bu-8.NBS 7.CH3

2、CH2CH2CH2-8.NBrOO正丁基N-溴代丁二酸酰亚胺二、选择一个正确的答案，填写在括号内。（15 分）(共 5 题，每题 3 分)1.苯环上最易发生卤代反应的是（C ）ABCDCH3CH3CH3CH3CH3CH3CH32.在水中溶解度最大的化合物为（A ）精品w o r d 学习资料可编辑资料-精心整理-欢迎下载-第 1 页，共 7 页ABCDCH2OHCH-OHCH2OHCH2OHCH-OHCH2OCH3CH2OHCH-OCH3CH2OCH3CH2OCH3CH-OCH3CH2OCH33.能与三氯化铁溶液发生显色反应的是（B ）ABCDCH3-COC2H5CH3-C-CH2-C-OC

3、2H5OOOCOOHCH2OH4.下列碳正离子的稳定性次序为（C ）：CH3CH2CH2CH3CHCH3CH3CHCH3A.B.C.D.5.下列化合物中酸性最强的是(D )ABCDOHOHNO2OHCH3OHNO2三、完成下列反应式或填写反应条件（21 分）（共 14 空格，每空格 1.5 分）1.CH3-CH-CH3BrKOHC2H5OHHBrH2O2()()1.CH3-CH2-CH2BrCH3CH=CH2,2.CH2CH3ClhvCl2NaHCO3H2O()()2.CHClCH3ClCHOHCH3Cl3.CH3CH2CCCH2CH3NaNH3液()精品w o r d 学习资料可编辑资料-

4、精心整理-欢迎下载-第 2 页，共 7 页文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5

5、O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4

6、U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A

7、1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编

8、码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H

9、2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z

10、10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J93.CCHH3CH2CCH2CH3H4.OCH3+HI()4.O H+CH3I5.CH3()HCH3HOHTsCl()EtOH

11、NaOH()5.HCH3HOTs(BH3)2 H2O2-NaOHCH3,6.(CH3)3C-BrNaOHHOClNaOH()()()6.(CH3)2C=CH2CH3CH3COHCH2ClCCH3H3COHCH2OH,7.NaICH3COCH3CH2CH3CH3BrH()8.(CH3)3Cl+NaCN()7.CH2CH3CH3HI8.CH2=C(CH3)2四、回答下列问题（12 分)(共 3 题，每题 4 分）1、比较下列化合物亲电反应的速度，请解释原因。苯酚、硝基苯、苯甲酸、苯、甲苯1、答:化合物亲电反应速度是:苯酚甲苯苯苯甲酸硝基苯。原因是:苯酚和甲苯存在推电子基团，属于第一类定位基，有利于

12、亲电反应，并且羟基比甲基推电子能力大；苯甲酸和硝基苯存在吸电子基团，属于第二类定位基，有不利于亲电反应，并且硝基比羧基吸电子能力大，硝基苯的亲电反应速度比苯甲酸慢。2、下列化合物进行碱性水解时的活性顺序：精品w o r d 学习资料可编辑资料-精心整理-欢迎下载-第 3 页，共 7 页文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1

13、ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D

14、10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9

15、文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:C

16、R3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6

17、N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10

18、HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U

19、4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9苄氯，对硝基苄氯，间硝基苄氯，对甲基苄氯，对甲氧基苄氯。答:进行碱性水解时的活性顺序是：对甲氧基苄氯对甲基苄氯苄氯间硝基苄氯对硝基苄氯。原因是:苄氯进行碱性水解是以SN1 历程进行反应，苯环上推电子有利于碱性水解，反之，不利于碱性水解，那么甲氧基和甲基推电子基团，并且推电子能力甲氧基大于甲基，对甲氧基苄氯的碱性水解反应速度比对甲基苄氯快；而硝基是吸电子基团，硝基苄氯的碱性水解反应速度比苄氯慢，邻、对位影响比间位大，所以，间硝基苄氯的碱性水解反应速度比对硝基苄氯快。3、卤烷与

20、氢氧化钠在水与乙醇混合物中进行反旅游区，指出哪些属于 SN2历程，哪些属于 SN1历程。产物的构型完全转化反应不分阶段，一步完成增加溶剂的含水量反应速度明显加快叔卤烷速度大于仲卤烷3、答:SN2SN2 SN1 SN1 五、合成（少于三个碳原子的烃类化合物、苯、无机原料任选）（25分）(共 5 题，每题 5 分)1 2.CH3CCHCH2CH3CH3ClCl精品w o r d 学习资料可编辑资料-精心整理-欢迎下载-第 4 页，共 7 页文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D1

21、0A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文

22、档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR

23、3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N

24、7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 H

25、R9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4

26、T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 Z

27、R4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9CH3CCHCH2CH31.CH3CCHHg2+H3O+CH3COCH3MgMgBr2FeMgBrCH2=CH2AgO2OOH3O+CH2CH2OHHBrH2SO4MgMgCH2CH2MgBrCH3COCH3H3O+H+CH2CH2C(CH3)2OHCH3IAlCl3CH3H2SO4100CH3SO3HFe2Cl2CH3SO

28、3HClClH2SO4CH3ClCl稀加热回流2.3.苯乙醇CH3CH2-C-CH2CH2CH3O精品w o r d 学习资料可编辑资料-精心整理-欢迎下载-第 5 页，共 7 页文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J

29、9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:

30、CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F

31、6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10

32、 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1

33、U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1

34、 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3

35、D10A1J9Br2FeBrMgEt2OCH2CH2OHOH3O+CH2=CH2Ag,O2O3.4.4.CHCHCH2=CH2+HBrCH3CH2Br2NaNH2NH3(l)CNaC Na2CH3CH2BrCH3CH2CCCH2CH3H3O+Hg2+CH3CH2COCH2CH2CH35.2,6-二硝基苯酚CH2=CHCH3CH(CH3)2cat.O2H3O+OHH2SO4100OHSO3H2HNO3H2SO4H2SO4OHNO2O2N加热回流稀5.六、推测结构。（10 分）(共 2 题，每题 5 分)1、有机物 A 和 B 分子式都为 C6H12，二者在室温下均能使Br2-CCl4褪色，但不能

36、被 KMnO4氧化，二者氢化产物都是3-甲基戊烷。但 A 与 HI 反应主要得到 3-甲基-3-碘戊烷，而 B 则得到 3-甲基-2-碘戊烷。试推导 A 和 B 的构造式。1、答：A 和 B 均能使 Br2-CCl4褪色，但不能被KMnO4氧化，说明 A 和 B 化合物是小环化合物，而没有不饱和键（如烯烃）；A 与 HI 反应主要得到3-甲基-3-碘戊烷，而 B 则得到 3-甲基-2-碘戊烷，二者氢化产物都是3-甲基戊烷，进一步说明 A 结构式是：B 结构式是：2、分子式为 C3H8O 的有机物，其红外光谱中3600-3100 区间有一强而宽的吸收带，其 HNMR 谱中=1.2 双峰（6H）；

37、=3.9 多峰（1H）；=4.9 单峰（1H）。试推导该有机物的结构式。2、答：有机物在红外光谱中3600-3100 区间有一强而宽的吸收带，说明存在羟基官能团；在 HNMR 谱中=1.2 双峰（6H），说明存在异丙基存在，那么有机物是异丙醇CH3CH2CH3H3CCH3H3C精品w o r d 学习资料可编辑资料-精心整理-欢迎下载-第 6 页，共 7 页文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3

38、D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J

39、9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:

40、CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F

41、6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10

42、 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1

43、U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1

44、 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9七、鉴别下列各组化合物及分离提纯。（9 分)(共 3 题，每题 3 分）1.1-丁炔 2-丁炔 1，3-丁二烯丁烷1.1-丁炔2-丁炔1，3-丁二烯丁烷银氨溶液白色沉淀不反应不反应不反应溴水褪色褪色不反应马来酸酐白色沉淀不反应2.CH3CH2-CH2OHCH-CH3CH3OHOHHCCH3CH3OCH(CH3)22H3CH2CCH2OHOH(H3C)2HCOCH(CH3)2CHOHCH3H3C溴水白色沉

45、淀白色沉淀不反应不反应碘仿试验有黄色沉淀生成没有三氯化铁显色不显色3.提纯：乙烯中含有少量乙炔3.通过银氨溶液中，除去小量乙炔，得到纯乙烯气体。精品w o r d 学习资料可编辑资料-精心整理-欢迎下载-第 7 页，共 7 页文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10

46、HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U

47、4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1

48、ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D

49、10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9

50、文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:CR3H2F6N7Z10 HR9K1U4T5O1 ZR4U3D10A1J9文档编码:C

文档加载中……请稍候！
如果长时间未打开，您也可以点击刷新试试。

下载文档到电脑，查找使用更方便

4.3 金币

版权申诉 word格式文档无特别注明外均可编辑修改；预览文档经过压缩，下载后原文更清晰！ 立即下载

配套讲稿：: 如PPT文件的首页显示word图标，表示该PPT已包含配套word讲稿。双击word图标可打开word文档。
特殊限制：: 部分文档作品中含有的国旗、国徽等图片，仅作为作品整体效果示例展示，禁止商用。设计者仅对作品中独创性部分享有著作权。
关键词：: 2021 有机化学第三学期模拟试题答案

淘文阁 - 分享文档赚钱的网站所有资源均是用户自行上传分享，仅供网友学习交流，未经上传用户书面授权，请勿作他用。

限制150内

关于本文

本文标题：2021年有机化学第三学期模拟试题及答案.pdf
链接地址：https://www.taowenge.com/p-56619007.html