大学《有机化学》课后习题答案.pdf

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1、.第一章绪论2.(1)(2)(5)易溶于水；(3)(4)(6)难溶于水。4.80*45%/12=3 80*7.5%/1=6 80*47.5%/19=2 C3H6F2 第二章有机化合物的结构本质及构性关系1.(1)sp3 (2)sp (3)sp2 (4)sp (5)sp3 (6)sp2第四章开 链 烃1.(1)2-甲基-4,5-二乙基庚烷 (2)3-甲基戊烷 (3)2,4-二甲基-3-乙基戊烷(4)(顺)-3-甲基-3-己烯 or Z-3-甲基-3-己烯 (12)3-甲基-1-庚烯-5-炔2.(2)(CH3)2CHCH2CH2CH3(1)(3)(CH3)2CHC CH(CH3)2CH3CH2CH

2、CH(CH2)4CH3CH3C2H5CH3C2H5(4)CH3CH2CH C(CH2)3CH3CH3(5)(CH3)2CHC CH(CH2)3CH3C2H5(6)C CH3CHHCH2CH2CH3(7)(8)(CH3)2CHC C C CCH(CH3)2(9)C CCH2 CHHHC CHC CH3CHCH2CH3CH3H3CCH3(10)C CH5C2C2H5CH3H3C7.(1)BrBrHHHH(2)BrHHBrBrBrHHHH(3)ClCl11.(1)CH3CHCH2CH2CH3(2)(CH3)2CCH2CH3BrBr(3)(CH3)2CCH(CH3)2Br(4)CH3CH2CC2H5B

3、rCH312.(6)CH3CH2CH2CBr2CH3(7)CH3CCH2CH3O(CH3)2CCH2CH3Cl(1)(2)CH3CH2CH2CH3(3)CH3CHCH2CH3OH(4)CH3COOH+COH3CH3C(5)CH3CH2CHCH3OSO3HCH3CH2CHCH3OH第 1 页，共 11 页.(8)(CH3)2CCHCH2+(CH3)2CCHCH2BrBr(9)(CH2CCHCH2)nCl+(CH2C)nClCHCH2(10)CHO14.(5)(3)(2)(1)(4)即：CH2=CHC+HCH3(CH3)3C+CH3CH2C+HCH3CH3CH2CH2C+H2(CH3)2CHC+H

4、2 16.(1)(2)(3)17.H2SO4,HgSO4H2OCH3CHOCHCHCH2CHOH(2)21AB.10（1）CH3-CH=CH2H/KMnO4CH3COOH（2）CH3-CCH+HBr（2mol）CH3CBr2CH3（3）CH3-CCH)mol1(HBrCH3-C=CH22BrCH3CBr2CH2Br Br 第四章环 烃2.1-戊烯1-戊炔戊烷Br2/CCl4 室温,避光 溴褪色 溴褪色Ag(NH3)2+灰白色1-丁炔2-丁炔丁烷Br2/CCl4 室温,避光溴褪色Ag(NH3)2+灰白色1,3-丁二烯1-己炔2,3-二甲基丁烷Br2/CCl4 溴褪色 溴褪色Ag(NH3)2+灰白

5、色第 2 页，共 11 页文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

6、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

7、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

8、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

9、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

10、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

11、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9.C(CH3)3CH3(1)(2)(3)3.(1)反式CH3Br(3)顺式4.CH3BrClCl+ClClCOOHH3CO2N(CH3)3CCOOH(1)(2)(3)(4)(5)(6)(7)BrC2H5C2H5Br+CH3COCH3(CH3)2CCH(CH3)2Br(8)1molCl2/h ,苯/无水 AlCl3 NHCOCH3NO

12、2CH3CH3SO3H(9)(10)7.(2)有芳香性10.第六章旋光异构6-3 2.(1)(2)(3)(4)(5)(6)第 3 页，共 11 页文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

13、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

14、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

15、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

16、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

17、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

18、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9.7.2.66120678.58.1820lcD第七章卤 代 烃2、ClClCl(2)4、第八章醇、酚、醚1.(1)3-甲基-3-戊烯-1-醇 (2)2-甲基苯酚 (3)2,5-庚二醇 (4)4-苯基-2-戊醇 (

19、5)2-溴-1-丙醇 (6)1-苯基乙醇(7)2-硝基-1-萘酚 (8)3-甲氧基苯甲 (9)1,2-二乙氧基乙烷（乙二醇二乙醚）(1)(2)3、4.(1)甲醇分子间氢键 (6)邻硝基苯酚分子氢键、分子间氢键5、(1)CH2IH3COOH(5)(6)HOOCH3H(7)6、AgNO3/乙醇,室温白AgNO3/乙醇，加热白第 4 页，共 11 页文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

20、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

21、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

22、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

23、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC

24、7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X

25、6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9.OHOH浓硫

26、酸,H3+O,OH浓硫酸,Br2/CCl4BrBrKOH/EtOH(1)(2)10、OHOClABCD第九章醛、酮、醌一、命名下列化合物。（1）CH3CHCH2CHOCH33-甲基丁醛（2）H3CCHCCH3CH3OZ-3-甲基-3-戊烯-2-酮（3）OHCHOCH34-甲基-2-羟基苯甲醛（4）CH3CCH3NNHC6H5丙酮苯腙三、写出下列反应方程式。（1）第 5 页，共 11 页文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3

27、X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:C

28、C7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3

29、X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:C

30、C7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3

31、X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:C

32、C7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3

33、X6 ZN3P1T9C9E9.OHCNOHCNH3O+OHCOOH（2）CH3CH2COCH3C2H5MgBrCH3CH2CCH2CH3CH3OMgBrCH3CH2CCH2CH3CH3OHH3O+干燥乙醚c（3）CH3CH2CHOH2CCH2OHOHCH3CH2CHOO+干HCl（4）CHOCH3CH2CHO稀NaOHCHOCHOOH+（5）CHOHCOHCH2OHHCOO-+浓NaOH+（6）CH3CHCHCCH3ONaBH4CH3CHCHCHCH3OHH2/NiCH3CH2CH2CHCH3OH(7)CCH3OZn-HgHClCH2CH3第 6 页，共 11 页文档编码:CC7V5C8Z8M

34、5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T

35、9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M

36、5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T

37、9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M

38、5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T

39、9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M

40、5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9.(8)CHOH2NOHCHNOH+(9)CH2CCH3I2NaOHCH2COO-CH3I +O(10)HOCH2CH2CH2CHOOOHCH3OHOOCH3干HCl干 HCl4.完成下列合成（无机试剂可任选）（1）由H2CCH2合成CH3CHCH2CH3BrH2CCH2H2CCH2H+/H2OHBr2.H3O+CH3CH2OHCH3CH2BrCH3CHCH2CH3OHCH3CHOPBr

41、3CH3CH2MgBrCH3CHCH2CH3BrMg/干燥乙醚Cu/1.CH3CH2MgBr /干燥乙醚（2）由HCCH合成CH3CH2CHCH3OHHCCHH2OCH3CH2MgClCH3CHOH2NiCH3CH2OH2.H+3OSOCl2CH3CH2CHCH3OHCH3CH2ClHg2+,H+Mg/干燥乙醚1.CH3CH2MgCl/干燥乙醚（3）由CH3CH2CH2OH合成CH3CH2CH2CCH2CH3O第 7 页，共 11 页文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文

42、档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O

43、1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文

44、档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O

45、1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文

46、档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O

47、1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文

48、档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9.CH3CH2CH2OHCH3CH2CH2OHCuSOCl2CH3CH2CHOCH3CH2CH2ClMgCH3CH2CH2MgCl/干燥乙醚CH3CH2CH2MgCl2.H3+OCH3CH2CH2CHCH2CH3OHKMnO4H+CH3CH2CH2CCH2CH3O干燥乙醚1.5.下列化合物哪些能发生碘仿反应？哪些能与NaHSO3发生加成反应？哪些能被Fehling试剂氧化？哪些能同羟胺作用生成肟？CH3CH2CHO CH3CH2CHCH3OHCH3CH2CH2OHC6H5CHCH3OHC6H5CCH3OOCH3H3C

49、CHOCH3COCH(CH3)2(CH3)3COHCH3COCH2COCH3碘仿反应：乙醛、甲基酮以及能被次碘酸钠氧化成乙醛、甲基酮的乙醇、仲醇。NaHSO3：醛和脂肪族甲基酮。Fehling试剂：氧化脂肪族醛，酮和芳香族醛无此反应。羟胺：羰基试剂，与所有含羰基醛酮反应。10、分子式为C6H12O的化合物A，可与羟胺反应，但不与Tollens试剂、饱和亚硫酸氢钠溶液反应。催化加氢得到分子式为的化合物B;B 和浓硫酸共热脱水生成分子式为的化合物C;C 经臭氧化后还原水解得到化合物 D 和 E;D 能发生碘仿反应，但不能发生银镜反应；E不能发生碘仿反应，但能发生银镜反应。试推测化合物和的构造式，并

50、写出各步反应式。C6H12O =(6*2+2)-12/2=1 可与羟胺反应，但不与Tollens试剂、饱和亚硫酸氢钠溶液反应:含羰基，脂肪族链状非甲基酮。催化加氢得到分子式为的化合物B:=0 B 为饱和链状脂肪族仲醇。B和浓硫酸共热脱水生成分子式为的化合物C：C为烯烃。C经臭氧化后还原水解得到化合物D和 E:D 和 E为醛酮。D能发生碘仿反应，但不能发生银镜反应：D为甲基酮E不能发生碘仿反应，但能发生银镜反应：E为超过 2 个碳原子的醛。D和 E分别为：第 8 页，共 11 页文档编码:CC7V5C8Z8M5 HO8O1B7Q3X6 ZN3P1T9C9E9文档编码:CC7V5C8Z8M5 HO