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2022年2018年高考全国卷理综化学卷试卷答案 .pdf

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1、2018 年普通高等学校招生全国统一考试理科综合能力测试（化学）可能用到的相对原子质量：H 1 Li 7 C 12 N 14 O 16 Na 23 S 32 Cl 35.5 Ar 40 Fe 56 I 127 一、选择题：本题共 13 个小题，每小题 6 分。共 78 分，在每小题给出的四个选项中，只有一项是符合题目要求的。7磷酸亚铁锂（LiFePO4）电池是新能源汽车的动力电池之一。采用湿法冶金工艺回收废旧磷酸亚铁锂电池正极片中的金属，其流程如下：下列叙述错误的是A合理处理废旧电池有利于保护环境和资源再利用B从“正极片”中可回收的金属元素有Al、Fe、Li C“沉淀”反应的金属离子为Fe3+

2、D上述流程中可用硫酸钠代替碳酸钠8下列说法错误的是A蔗糖、果糖和麦芽糖均为双糖B酶是一类具有高选择催化性能的蛋白质C植物油含不饱和脂肪酸酯，能使Br2/CCl4褪色D淀粉和纤维素水解的最终产物均为葡萄糖9在生成和纯化乙酸乙酯的实验过程中，下列操作未涉及的是10NA是阿伏加德罗常数的值。下列说法正确的是A16.25 g FeCl3水解形成的Fe（OH）3胶体粒子数为0.1 NAB22.4 L（标准状况）氩气含有的质子数为18NAC92.0 g 甘油（丙三醇）中含有羟基数为1.0NAD1.0 mol CH4与 Cl2在光照下反应生成的CH3Cl 分子数为1.0NA 11环之间共用一个碳原子的化合物

3、称为螺环化合物，螺2，2戊烷（）是最简单的一种。下列关于该化合物的说法错误的是学&科网A与环戊烯互为同分异构体B二氯代物超过两种C所有碳原子均处同一平面D生成 1 mol C5H12至少需要2 mol H212主族元素W、X、Y、Z 的原子序数依次增加，且均不大于20。W、X、Z 最外层电子数之和为10；W 与 Y 同族；W 与 Z 形成的化合物可与浓硫酸反应，其生成物可腐蚀玻璃。下列说法正确的是A常温常压下X 的单质为气态BZ 的氢化物为离子化合物CY 和 Z 形成的化合物的水溶液呈碱性DW 与 Y 具有相同的最高化合价13最近我国科学家设计了一种CO2+H2S协同转化装置，实现对天然气中C

4、O2和 H2S 的高效去除。示意图如图所示，其中电极分别为ZnO石墨烯（石墨烯包裹的ZnO）和石墨烯，石墨烯电极区发生反应为：文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1

5、HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A

6、8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文

7、档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T

8、10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5

9、 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W

10、2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R

11、6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5EDTA-Fe2+e-=EDTA-Fe3+2EDTA-Fe3+H2S=2H+S+2EDTA-Fe2+该装置工作时，下列叙述错误的是A阴极的电极反应：CO2+2H+2e-=CO+H2O B协同转化总反应：CO2+H2S=CO+H2O+S C石墨烯上的电势比ZnO石墨烯上的低D若采用 Fe3+/Fe2+取代 EDTA-Fe3+/EDTA-Fe2+，溶液需为酸性26（14 分）醋酸亚铬（CH3COO）2Cr 2H2O为砖红色晶体，难溶于冷水，易溶于酸，

12、在气体分析中用作氧气吸收剂。一般制备方法是先在封闭体系中利用金属锌作还原剂，将三价铬还原为二价铬；二价铬再与醋酸钠溶液作用即可制得醋酸亚铬。实验装置如图所示。回答下列问题：学科%网（1）实验中所用蒸馏水均需经煮沸后迅速冷却，目的是_。仪器 a的名称是 _。（2）将过量锌粒和氯化铬固体置于c 中，加入少量蒸馏水，按图连接好装置，打开K1、K2，关闭 K3。c 中溶液由绿色逐渐变为亮蓝色，该反应的离子方程式为_。同时 c 中有气体产生，该气体的作用是_。（3）打开 K3，关闭 K1 和 K2。c 中亮蓝色溶液流入d，其原因是 _；d 中析出砖红色沉淀。为使沉淀充分析出并分离，需采用的操作是_、_、

13、洗涤、干燥。文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5

14、ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2

15、V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6

16、E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:C

17、T2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10

18、G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D

19、10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S

20、6E5 ZC9D10T10O10G5（4）指出装置d 可能存在的缺点_。27（14 分）焦亚硫酸钠（Na2S2O5）在医药、橡胶、印染、食品等方面应用广泛。回答下列问题：（1）生产 Na2S2O5，通常是由NaHSO3过饱和溶液经结晶脱水制得。写出该过程的化学方程式_。（2）利用烟道气中的SO2生产 Na2S2O5的工艺为：pH=4.1 时，中为 _溶液（写化学式）。工艺中加入Na2CO3固体、并再次充入SO2的目的是 _。（3）制备 Na2S2O5也可采用三室膜电解技术，装置如图所示，其中SO2碱吸收液中含有NaHSO3和 Na2SO3。阳极的电极反应式为_。电解后，_室的 NaHSO3浓度

21、增加。将该室溶液进行结晶脱水，可得到Na2S2O5。（4）Na2S2O5可用作食品的抗氧化剂。在测定某葡萄酒中Na2S2O5残留量时，取 50.00 mL 葡萄酒样品，用 0.01000 mol L-1的碘标准液滴定至终点，消耗10.00 mL。滴定反应的离子方程式为_，该样品中Na2S2O5的残留量为 _g L-1（以 SO2计）。28（15 分）采用 N2O5为硝化剂是一种新型的绿色硝化技术，在含能材料、医药等工业中得到广泛应用。回答下列问题：学科*网（1）1840 年 Devil 用干燥的氯气通过干燥的硝酸银，得到N2O5，该反应的氧化产物是一种气体，其分子式为_。（2）F.Daniel

22、s 等曾利用测压法在刚性反应器中研究了25时 N2O5（g）分解反应：文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文

23、档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T

24、10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5

25、 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W

26、2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R

27、6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:

28、CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O1

29、0G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5其中 NO2二聚为 N2O4的反应可以迅速达到平衡。体系的总压强p 随时间 t 的变化如下表所示（t=时，N2O5（g）完全分解）：t/min 0 40 80 160 260 1300 1700 p/kPa 35.8 40.3 42.5 45.9 49.2 61.2 62.3 63.1 已知：2N2O5（g）2N2O4（g）+O2（g）H1=-4.4 kJ mol-12NO2（g）N2O4（g）H 2=-55.3 kJ mol-1则反应 N2O5（g）=2NO2（g）+12O2（g）的 H=_ kJm

30、ol-1。研究表明，N2O5（g）分解的反应速率v=2 10-325N Op（kPa min-1）。t=62 min 时，测得体系中2Op=2.9 kPa，则此时的25N Op=_ kPa，v=_ kPa min-1。若提高反应温度至35，则 N2O5（g）完全分解后体系压强p（35）_63.1 kPa（填“大于”“等于”或“小于”），原因是 _。25时 N2O4（g）2NO2（g）反应的平衡常数Kp=_kPa（Kp为以分压表示的平衡常数，计算结果保留1 位小数）。（3）对于反应2N2O5（g）4NO2（g）+O2（g），R.A.Ogg 提出如下反应历程：第一步N2O5NO3+NO2快速平衡第

31、二步NO2+NO3 NO+NO2+O2 慢反应第三步NO+NO32NO2快反应其中可近似认为第二步反应不影响第一步的平衡。下列表述正确的是_（填标号）。Av（第一步的逆反应）v（第二步反应）B反应的中间产物只有NO3C第二步中NO2与 NO3的碰撞仅部分有效D第三步反应活化能较高35 化学选修 3：物质结构与性质（15 分）Li 是最轻的固体金属，采用Li 作为负极材料的电池具有小而轻、能量密度大等优良性能，得到广泛应用。回答下列问题：（1）下列 Li 原子电子排布图表示的状态中，能量最低和最高的分别为_、_（填标号）。A文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D1

32、0T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6

33、E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR

34、8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A

35、2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编

36、码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10

37、O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 Z

38、C9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5BCD（2）Li+与 H-具有相同的电子构型，

39、r（Li+）小于 r（H-），原因是 _。（3）LiAlH4是有机合成中常用的还原剂，LiAlH4中的阴离子空间构型是_、中心原子的杂化形式为_。LiAlH4中，存在 _（填标号）。A离子键B键C键D氢键（4）Li2O 是离子晶体，其晶格能可通过图（a）的Born-Haber 循环计算得到。可知，Li 原子的第一电离能为kJ mol-1，O=O 键键能为kJ mol-1，Li2O 晶格能为kJ mol-1。（5）Li2O 具有反萤石结构，晶胞如图（b）所示。已知晶胞参数为0.4665 nm，阿伏加德罗常数的值为NA，则 Li2O 的密度为 _g cm-3（列出计算式）。36化学选修 5：有机

40、化学基础（15 分）化合物 W 可用作高分子膨胀剂，一种合成路线如下：文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文

41、档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T

42、10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5

43、 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W

44、2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R

45、6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:

46、CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O1

47、0G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5回答下列问题：（1）A 的化学名称为。（2）的反应类型是。（3）反应所需试剂、条件分别为。（4）G 的分子式为。文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W

48、2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R

49、6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:

50、CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O10G5文档编码:CT2A8A2R6E1 HR8W2V10S6E5 ZC9D10T10O1

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