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2022年2018年高考全国卷Ⅲ化学 .pdf

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1、2018年普通高等学校招生全国统一考试（）化学可能用到的相对原子质量：H 1 C 12 N 14 O 16 Na 23 Mg 24 Al 27 S 32 Cr 52 Zn 65 I 127 一、选择题：本题共13 个小题，每小题6 分，共 78 分。在每小题给出的四个选项中，只有一项是符合题目要求的。7化学与生活密切相关。下列说法错误的是A泡沫灭火器可用于一般的起火，也适用于电器起火B疫苗一般应冷藏存放，以避免蛋白质变性C家庭装修时用水性漆替代传统的油性漆，有利于健康及环境D电热水器用镁棒防止内胆腐蚀，原理是牺牲阳极的阴极保护法8下列叙述正确的是A24 g 镁与 27 g 铝中，含有相同的质子

2、数B同等质量的氧气和臭氧中，电子数相同C1 mol 重水与 1 mol 水中，中子数比为21 D1 mol 乙烷和 1 mol 乙烯中，化学键数相同9苯乙烯是重要的化工原料。下列有关苯乙烯的说法错误的是A与液溴混合后加入铁粉可发生取代反应B能使酸性高锰酸钾溶液褪色C与氯化氢反应可以生成氯代苯乙烯D在催化剂存在下可以制得聚苯乙烯10下列实验操作不当的是A用稀硫酸和锌粒制取H2时，加几滴CuSO4溶液以加快反应速率B用标准HCl 溶液滴定NaHCO3溶液来测定其浓度，选择酚酞为指示剂C用铂丝蘸取某碱金属的盐溶液灼烧，火焰呈黄色，证明其中含有Na+D常压蒸馏时，加入液体的体积不超过圆底烧瓶容积的三分

3、之二11 一种可充电锂-空气电池如图所示。当电池放电时，O2与 Li+在多孔碳材料电极处生成Li2O2-x（x=0 或 1）。下列说法正确的是A放电时，多孔碳材料电极为负极B放电时，外电路电子由多孔碳材料电极流向锂电极C充电时，电解质溶液中Li+向多孔碳材料区迁移D充电时，电池总反应为Li2O2-x=2Li+（1-2x）O212用 0.100 mol L-1 AgNO3滴定 50.0 mL 0.0500 mol L-1 Cl-溶液的滴定曲线如图所示。下列有关描述错误的是A根据曲线数据计算可知Ksp(AgCl)的数量级为10-10B曲线上各点的溶液满足关系式c(Ag+)c(Cl-)=Ksp(Ag

4、Cl)C相同实验条件下，若改为0.0400 molL-1 Cl-，反应终点c 移到 a D相同实验条件下，若改为0.0500 molL-1 Br-，反应终点c 向 b 方向移动13 W、X、Y、Z 均为短周期元素且原子序数依次增大，元素X 和 Z 同族。盐YZW 与浓盐酸反应，有黄绿色气体产生，此气体同冷烧碱溶液作用，可得到YZW 的溶液。下列说法正确的是A原子半径大小为WXYZ BX 的氢化物水溶液酸性强于Z 的CY2W2与 ZW2均含有非极性共价键D标准状况下W 的单质状态与X 的相同三、非选择题：共174 分。第 2232 题为必考题，每个试题考生都必须作答。第3338 题为选考题，考生

5、文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S

6、4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8

7、R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10

8、Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D

9、9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5

10、F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M

11、10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2根据要求作答。（一）必考题：共129 分。26（14 分）硫代硫酸钠晶体（Na2S2O3 5H2O，M=248 g mol-1）可用作定影剂、还原剂。回答下列问题：（1）已知：Ksp(BaSO4)=1.1 10-10，Ksp(BaS2O3)=4.1 10-5。市售

12、硫代硫酸钠中常含有硫酸根杂质，选用下列试剂设计实验方案进行检验：试剂：稀盐酸、稀H2SO4、BaCl2溶液、Na2CO3溶液、H2O2溶液实验步骤现象取少量样品，加入除氧蒸馏水固体完全溶解得无色澄清溶液_ _，有刺激性气体产生静置，_ _（2）利用 K2Cr2O7标准溶液定量测定硫代硫酸钠的纯度。测定步骤如下：溶液配制：称取1.2000 g 某硫代硫酸钠晶体样品，用新煮沸并冷却的蒸馏水在_中溶解，完全溶解后，全部转移至100 mL 的_中，加蒸馏水至_。滴定：取0.00950 mol L-1的 K2Cr2O7标准溶液20.00 mL，硫酸酸化后加入过量KI，发生反应：Cr2O72-+6I-+1

13、4H+3I2+2Cr3+7H2O。然后用硫代硫酸钠样品溶液滴定至淡黄绿色，发生反应：I2+2S2O32-S4O62-+2I-。加入淀粉溶液作为指示剂，继续滴定，当溶液 _，即为终点。平行滴定3 次，样品溶液的平均用量为24.80 mL，则样品纯度为_%（保留 1 位小数）。27（14 分）KIO3是一种重要的无机化合物，可作为食盐中的补碘剂。回答下列问题：（1）KIO3的化学名称是_。（2）利用“KClO3氧化法”制备 KIO3工艺流程如下图所示：“酸化反应”所得产物有KH(IO3)2、Cl2和 KCl。“逐 Cl2”采用的方法是_。“滤液”中的溶质主要是 _。“调 pH”中发生反应的化学方程

14、式为_。（3）KIO3也可采用“电解法”制备，装置如图所示。写出电解时阴极的电极反应式_。电解过程中通过阳离子交换膜的离子主要为_，其迁移方向是_。与“电解法”相比，“KClO3氧化法”的主要不足之处有_（写出一点）。文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R

15、4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y

16、2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9

17、S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F

18、8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M1

19、0Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8

20、D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y228（15 分）三氯氢硅（SiHCl3）是制备

21、硅烷、多晶硅的重要原料。回答下列问题：（1）SiHCl3在常温常压下为易挥发的无色透明液体，遇潮气时发烟生成(HSiO)2O 等，写出该反应的化学方程式 _。（2）SiHCl3在催化剂作用下发生反应：2SiHCl3(g)SiH2Cl2(g)+SiCl4(g)H1=48 kJ mol-1 3SiH2Cl2(g)SiH4(g)+2SiHCl3(g)H2=-30 kJ mol-1 则反应 4SiHCl3(g)SiH4(g)+3SiCl4(g)的 H=_ kJmol-1。（3）对于反应2SiHCl3(g)SiH2Cl2(g)+SiCl4(g)，采用大孔弱碱性阴离子交换树脂催化剂，在323 K和 343

22、 K 时 SiHCl3的转化率随时间变化的结果如图所示。343 K 时反应的平衡转化率=_%。平衡常数K343 K=_（保留 2 位小数）。在 343 K 下：要提高SiHCl3转化率，可采取的措施是_；要缩短反应达到平衡的时间，可采取的措施有_、_。比较a、b 处反应速率大小：va_vb（填“大于”“小于”或“等于”）。反应速率v=v正-v逆=32SiHClk x正-224SiH ClSiClk xx逆，k正、k逆分别为正、逆向反应速率常数，x 为物质的量分数，计算a处vv正逆=_（保留 1 位小数）。（二）选考题：共45 分。请考生从2 道物理题、2 道化学题、2 道生物题中每科任选一题作

23、答。如果多做，文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:C

24、N6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO

25、1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4

26、E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码

27、:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8

28、HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 Z

29、Z4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2则每科按所做的第一题计分。35 化学选修 3：物质结构与性质（15 分）锌在工业中有重要作用，也是人体必需的微量元素。回答下列问题：（1）Zn 原子核外电子排布式为_。（2）黄铜是人类最早使用的合金之一，主要由 Zn 和 Cu 组成。第一电离能1（

30、Zn）_1（Cu)(填“大于”或“小于”)。原因是 _。（3）ZnF2具有较高的熔点（872)，其化学键类型是_；ZnF2不溶于有机溶剂而ZnCl2、ZnBr2、ZnI2能够溶于乙醇、乙醚等有机溶剂，原因是_。（4）中华本草等中医典籍中，记载了炉甘石（ZnCO3）入药，可用于治疗皮肤炎症或表面创伤。ZnCO3中，阴离子空间构型为_，C 原子的杂化形式为_。（5）金属 Zn 晶体中的原子堆积方式如图所示，这种堆积方式称为_。六棱柱底边边长为 a cm，高为 c cm，阿伏加德罗常数的值为NA，Zn 的密度为 _gcm3（列出计算式）。36 化学选修 5：有机化学基础（15 分）近来有报道，碘代

31、化合物E 与化合物H 在 Cr-Ni 催化下可以发生偶联反应，合成一种多官能团的化合物 Y，其合成路线如下：已知：回答下列问题：（1）A 的化学名称是_。（2）B 为单氯代烃，由B 生成 C 的化学方程式为_。文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ

32、4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编

33、码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8

34、 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4

35、ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文

36、档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4

37、T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2（3）由 A 生成 B、G 生成 H 的反应类型分别是

38、_、_。（4）D 的结构简式为_。（5）Y 中含氧官能团的名称为_。（6）E 与 F 在 Cr-Ni 催化下也可以发生偶联反应，产物的结构简式为_。（7）X 与 D 互为同分异构体，且具有完全相同官能团。X 的核磁共振氢谱显示三种不同化学环境的氢，其峰面积之比为332。写出 3 种符合上述条件的X 的结构简式 _。参考答案7A 8B 9C 10B 11D 12C 13D 26（14 分）（1）加入过量稀盐酸出现乳黄色浑浊（吸）取上层清液，滴入BaCl2溶液产生白色沉淀（2）烧杯容量瓶刻度蓝色退去95.0（3）Zn+Cd2+Zn2+Cd（4）Zn2+2eZn 溶浸27（14分）（1）碘酸钾（2）

39、加热KCl KH(IO3)2+KOH2KIO3+H2O 或（HIO3+KOHKIO3+H2O）（3）2H2O+2e2OH+H2K+a 到 b 产生 Cl2易污染环境等28（15 分）（1）2SiHCl3+3H2O(HSiO)2O+6HCl（2）114（3）22 0.02 及时移去产物改进催化剂提高反应物压强（浓度）大于1.3 35（15 分）文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:

40、CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 H

41、O1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ

42、4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编

43、码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8

44、 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4

45、ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文

46、档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2（1）Ar3d104s2（2）大于Zn 核外电子排布为全满稳定结构，较难失电子（3）离子键ZnF2为离子化合物，ZnCl2、ZnBr2、ZnI2的化学键以共价键为主、极性较小（4）平面三角形sp2（5）六方最密堆积（A3型）2A656436Na c36（15 分）（1）丙炔（2）（3）取代反应、加成反应（4）（5）羟基、酯基（6）（7）、文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6

47、A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O

48、7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3

49、B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:C

50、N6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO1O7W5F8R4 ZZ4E3B5M10Y2文档编码:CN6A8D9S4T8 HO

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