聚酯PET热灌装饮料瓶基础知识(PPT43页).ppt
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1、Range范围范围Advantages效益效益Specifics细节细节Heat-resistant bottles热灌装瓶Description描述描述SpecificsBasicprinciple基本原理基本原理Hot-filling热灌装热灌装Pasteurization巴氏杀菌巴氏杀菌Purposeofheat-setting加热设定的目的加热设定的目的Wateruptakeconcept吸水概念吸水概念Basicprinciple基本原理基本原理nBlow-moldingofPETbottlestowithstandhightemperatureswithnodeformation所
2、吹制的所吹制的PET瓶必须能承受高温而不变形瓶必须能承受高温而不变形ustandard bottles are deformed under the effect of heat from 60 C upwardsu标准的瓶子加热至60 C 以上开始变形uadaptation of heat conditioning and blow-molding processes enables bottles to withstand temperatures of up to 88Cu适当的加热条件和吹瓶工艺能使瓶子承受88C的温度nApplicationtothepackagingofsensit
3、ivedrinkssuchasisotonics,fruitjuices,teasetc.n应用作敏感饮料包装例如应用作敏感饮料包装例如n等压、果汁、茶等等压、果汁、茶等uHotfilling 热灌装uPasteurization 巴氏杀菌Hotfilling热灌装热灌装nOperatingmethod操作方法操作方法uThe liquid is raised to a temperature enabling it to be sterilizedu液体温度提升至能灭菌的温度 uThe bottle is filled at this temperature(up to 88C)u瓶子在这温
4、度下(高至 88C)灌装uSterlization of the cap is obtained by contact with the hot liquidu瓶盖与热的液体接触进行灭菌 uGradual cooling 分段冷却 nSpecificstressfactorsn特殊的应力因素特殊的应力因素uInflation then collapsing 膨胀后扁平uLocal deformation 局部变形uContraction 收缩Inflationthencollapsing膨胀后扁平膨胀后扁平nRiseintemperatureofthematerialcombinedwithm
5、echanicalstressn含有机械应力的材料温度升高含有机械应力的材料温度升高umaterial is softened,easily deformedu材料变软,容易变形uHydrostatic pressure exerted by the liquid on the walls:bottle inflationu液体在瓶壁上产生向外的静压:瓶膨胀 uExpansion of the air in the head area:increased inflation u顶部空气膨胀:增加膨胀uEffect of internal vacuum pressure resulting fr
6、om the cooling of the liquid and the air in the head area:phenomenon known as“collapsing”u由液体和瓶颈空气冷却而产生真空压力:已知现象如 “扁平”Localdeformation局部变形局部变形nStressexertedlocallyduringpackagingn在包装过程中外界压力局部地在包装过程中外界压力局部地作用作用uMechanical stress exerted by the cap:risk of deformationu封盖的机械应力:变形的风险uConveying of the fi
7、lled bottles while still hot:deformation on contact with the transport and guiding equipment u已灌装的瓶输送静止受热:与输送链条接触和导向处变形uContact of the unstretched neck with the hot liquid:the material becomes plastic,deformation is possibleu未拉伸的瓶颈与热的液体接触:材料成为塑料态,有可能变形Contraction收缩收缩nDeformationresultingfromtheintri
8、nsicpropertiesofthematerial材料的固有特性导致变形材料的固有特性导致变形u Release under the effect of heat of the stress factors caused by stretching and which remain in the material after blow-moldingu拉伸和吹塑后残留在材料里的应力在热量的作用下被释放u Deformation of the material which naturally tends towards a state in which the level of stress
9、 is lowestu材料的变形自然趋向于低应力水平的状态u“Memory”effectu“记忆”效应Pasteurization巴氏杀菌巴氏杀菌nPrinciple原理原理uFilling at temperatures close to ambient 灌注温度接近于周围环境uPasteurization tunnel.Feethrough of the bottle filled and capped under hot showers.A temperature of 75C is maintained in the core of the liquid for 10 min(25 m
10、in at 65C for carbonated drinks)u已灌注和封盖的瓶子通过有热喷淋的隧道进行巴氏杀菌,液体中心温度维持在75C、10分钟(汽水为65C、25分钟)uCooling under showers at between 20 and 40 Cu喷淋冷却至20 40 C之间nSpecificstressfactorsn特殊的应力因素特殊的应力因素uInflation膨胀uContraction收缩Inflation膨胀膨胀nRiseintemperatureofthematerialcombinedwithmechanicalstressn含有机械应力的材料温度升高含有机
11、械应力的材料温度升高uexpansion of the air in the head area:inflation of the bottleu顶部区域空气膨胀:瓶子膨胀uRelease of CO2 by carbonated drinks:increased inflation u碳酸饮料CO2 释放:增加膨胀uInternal pressure persists after cooling,despite the decrease in volume of the liquid.u冷却后内部压力持续,尽管液体体积减少Contraction收缩收缩nDeformationresultin
12、gfromtheintrinsicpropertiesofthematerial材料的固有特性导致变形材料的固有特性导致变形u Release under the effect of heat of the stress factors caused by stretching and which remain in the material after blow-moldingu拉伸和吹塑后残留在材料里的应力在热量的作用下被释放u Deformation of the material which naturally tends towards a state in which the le
13、vel of stress is lowestu材料的变形自然趋向于低应力水平的状态u“Memory”effectu“记忆”效应Purposeofheat-setting加热设定的目的加热设定的目的nImprovementinheatresistance改进耐热性改进耐热性uIncrease in crystallinity增加结晶度Prevention of contraction防止收缩Limited generation of induced stress(process and preform design)限制诱导应力的产生(生产和瓶坯设计)Relaxation of residua
14、l induced stress(molds)残留的诱导应力松弛(模具)Increaseincrystallinity增加结晶度增加结晶度nOffsetoftheglasstransitiontemperaturen抵消玻璃化转变温度抵消玻璃化转变温度uGlass transition temperature raised to a level higher than the temperatures to which the bottle will be subjected u玻璃化温度升高至较高程度会影响瓶子nEnhanceddevelopmentofspheruliticcrystall
15、ization球状结晶的发展增多球状结晶的发展增多Operating rangeOperating rangeGlass transition temp.玻璃化温度玻璃化温度Glass transition temp.玻璃化温度玻璃化温度Developmentofspheruliticcrystallinity球状结晶的发展球状结晶的发展nEnhancedheat-conditioningofthepreformintheovenandhotmold增大加热炉和模具内瓶坯的加热增大加热炉和模具内瓶坯的加热温度温度nHighdegreeofcrystallinity提高结晶度提高结晶度uPref
16、orm undergoes powerful heat-conditioning before being quickly transferred for blow-molding.瓶坯进入吹模之前充分受热uEnhances the generation of spherulitic crystallization in the bottle on contact with the hot mold after the start of crystallization caused by bi-orientation.u当由拉伸引起的结晶开始后瓶与热模接触所产生的球状结晶增加u30 to 35
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