天然气处理工艺,设备及原理讲解学习.ppt
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1、天然气处理工艺,设备及原理脱硫脱硫SulfurRemovalSulfurRemoval脱水脱水DehydrationDehydration硫磺回收硫磺回收SulfurRecoverySulfurRecovery尾气处理尾气处理TailGasTailGasTreatmentTreatment主体工艺主体工艺主体工艺主体工艺Main ProcessMain Process空氮站空氮站Air&N2StationAir&N2Station锅炉给水框架锅炉给水框架BoilerFeedwaterBoilerFeedwater燃料气系统燃料气系统FuelGasSys.FuelGasSys.火炬及放空系统火炬
2、及放空系统Flare&VentSys.Flare&VentSys.硫磺成型及储存硫磺成型及储存SulfurStorage&SulfurStorage&FormingForming商业计量站商业计量站GasCommercialGasCommercialMeteringStationMeteringStation水处理系统水处理系统WaterTreatmentSys.WaterTreatmentSys.气田水处理系统气田水处理系统ProducedwaterProducedwaterTreatmentTreatment公用工程及辅助设施公用工程及辅助设施公用工程及辅助设施公用工程及辅助设施Utili
3、ties&Auxiliary FacilitiesUtilities&Auxiliary Facilities自控机柜间自控机柜间CentralControlCentralControlRoomRoom35kV35kV变电站变电站35kVSubstation35kVSubstation循环水系统循环水系统CoolingWaterSys.CoolingWaterSys.消防水给水系统消防水给水系统FireWaterFireWaterSupplySys.SupplySys.天然气处理厂GasTreatmentPlant工厂组成PlantComponents2Gas Plant overviewSu
4、lfur Sulfur Removal Removal UnitUnit 脱硫脱硫装置装置(2)(2)Tail Gas Treatment&Tail Gas Treatment&Sour H2O Stripping Sour H2O Stripping 尾气尾气处理处理&酸酸H2OH2O汽提汽提(1)(1)Sulfur Sulfur Recovery Recovery UnitUnit硫磺回收硫磺回收装置装置(1)(1)Sulfur Sulfur Removal Removal Unit Unit 脱硫脱硫装置装置(1)(1)Commercial Metering StationCommerc
5、ial Metering Station商业计量站商业计量站Dehydration Dehydration 三甘醇脱水三甘醇脱水Liquid Sulfur Liquid Sulfur Storage TanksStorage Tanks液硫储罐液硫储罐IncineratorIncinerator 灼烧炉灼烧炉Sulfur Sulfur FormingForming 硫硫成型成型IncineratorIncinerator灼烧炉灼烧炉Sulfur Sulfur Recovery Recovery UnitUnit 硫磺回硫磺回收装置收装置(2)(2)Tail Gas Treatment&Tail
6、 Gas Treatment&Sour Water StrippingSour Water Stripping尾气尾气处理处理&酸酸H2OH2O汽提汽提(2)(2)FeedGasFromFeedGasFromGasTerminalGasTerminalStationStation 来自末站的原来自末站的原料气料气WetTreatedGasWetTreatedGas 处理湿气处理湿气AcidGasAcidGas酸气酸气AcidGasAcidGas酸气酸气AcidGasAcidGas酸气酸气SalesGastoGridSalesGastoGrid商品气至管网商品气至管网ProductSulfurt
7、oStorageProductSulfurtoStorage 硫磺产品储存硫磺产品储存VenttoAtm.VenttoAtm.VenttoAtm.VenttoAtm.AcidGasAcidGas酸气酸气6脱硫目的Purpose通过气-液吸收、气-固吸附和化学转化等途径除去天然气中的含硫化合物和部分CO2,使其达到商品天然气管输标准。ToremovesulfurcompoundsandexcessiveCO2fromsournaturalgasbymeansofgas-liquidabsorption,gas-solidadsorptionandchemicalconversionssothat
8、thegasmeetsthepipelinetransportationspecifications.脱硫工艺方法本厂使用砜胺溶液Sulfinol-M(萨菲诺-M)进行脱硫TheplantusesSulfinol-Mtoremovesulfur.溶液組份:甲基二乙醇胺50%,环丁砜15%,水35%。CompositionoftheSolvent:50%MDEA,15%sulfolane,35%water Sulfur Removal Unit脱硫装置脱硫装置再生塔Regenerator闪蒸罐FlashTank主吸收塔Main Absorber回流泵过滤分离器FeedgasFilter分离部分分
9、离部分 Separation Section去除原料气中的大量水和杂质Remove water and impurities from the feed gas吸收部分吸收部分 Absorption Sectin砜胺溶液和原料气在吸收内逆向接触,吸收H2S、CO2和部分有机硫(脱硫)The sulfinol-M countercurrents with feed gas and absorbs H2S,CO2 and part of organic sulfur(sulfur removal)闪蒸部分蒸部分 Flash Section闪蒸出砜胺富液中夹带的碳氢化合物Flash hydrocar
10、bon out of the rich sulfinol-M再生部分再生部分 Regeneration Section用加热的方式解析出富液中的酸气,The rich sulfinol-M is regenerated by heating it to drive off acid gas富液再生富液再生Rich sulfinol-M regeneration将再生后的贫液打回吸收塔循环使用The lean sulfinol-M regenerated is routed to absorber for recycling湿净化气去脱水单元WetTreatedgastodehydrationu
11、nit解析出的酸气送入硫磺回收单元Acidgastosulfurrecoveryunit9Sulfur Removal Unit脱硫脱硫设备清清单塔塔脱硫吸收塔闪蒸气吸收塔再生塔罐罐原料气分离器湿净化气分离器闪蒸罐回流罐砜胺液排放罐凝结水分离器nEquipment List-Sulfur Removal vColumnsMainAbsorberColumnFlashGasAbsorberColumnRegeneratorColumnvDrumsFeedGasSeparatorDrumWetTreatedGasK.O.DrumFlashDrumRefluxDrumSulfinolDrainDru
12、mCondensateWaterSeparator10Sulfur Removal Unit换热器和冷凝器器和冷凝器l贫富砜胺液换热器l贫砜胺液冷却器l贫砜胺液后冷却器l再生塔重沸器l塔顶冷凝器l塔顶后冷器过滤器器l原料气过滤分离器l砜胺液机械过滤器l活性炭过滤器l砜胺液后过滤器l排放溶液过滤器vExchangers&CoolerslLean/RichSulfinolExchangerslLeanSulfinolCoolerlLeanSulfinolTrimCoolerlRegeneratorReboilerlOverheadCondenserlOverheadTrimCoolervFilte
13、rslFeedGasFilterslLeanSulfinolFilterlActivatedCarbonFilterlSulfinolTrimFilterlDrainedSulfinolFilter11Sulfur Removal UnitvPumps&DriversLowPressureLeanSulfinolPumpsHighPressureLeanSulfinolPumpsRefluxPumpsDrainedSulfinolPumpPowerRecoveryTurbine泵和驱动器v低压贫砜胺液泵v高压贫砜胺液泵v回流泵v排放溶液泵v富砜胺液能量回收透平)12ENVIRONMENTFOC
14、US环保关注点气体污染:H2S泄漏、含硫闪蒸气泄漏Gaspollution:H2Sleakage,flashgasleakage固体污染:固废物堆放、Solidpollution:solidwastepiles液体污染:脱硫溶液泄漏、化学药剂泄漏、Liquidpollution:desulfurizationsolutionleakage,chemicalleakage热辐射:换热器、重沸器、蒸汽泄漏HeatRadiation:heatexchanger,re-boilerandsteamleakage噪声污染:管线噪声、机械噪声Noisepollution:ductnoise,mechani
15、calnoise脱水脱水单元元Dehydration UnitGas Plant overviewSulfur Sulfur Removal Removal UnitUnit 脱硫脱硫装置装置(2)(2)Tail Gas Treatment&Tail Gas Treatment&Sour H2O Stripping Sour H2O Stripping 尾气尾气处理处理&酸酸H2OH2O汽提汽提(1)(1)Sulfur Sulfur Recovery Recovery UnitUnit硫磺回收硫磺回收装置装置(1)(1)Sulfur Sulfur Removal Removal Unit Un
16、it 脱硫脱硫装置装置(1)(1)Commercial Metering StationCommercial Metering Station商业计量站商业计量站Dehydration Dehydration 三甘醇脱水三甘醇脱水Liquid Sulfur Liquid Sulfur Storage TanksStorage Tanks液硫储罐液硫储罐IncineratorIncinerator 灼烧炉灼烧炉Sulfur Sulfur FormingForming 硫硫成型成型IncineratorIncinerator灼烧炉灼烧炉Sulfur Sulfur Recovery Recovery
17、 UnitUnit 硫磺回硫磺回收装置收装置(2)(2)Tail Gas Treatment&Tail Gas Treatment&Sour Water StrippingSour Water Stripping尾气尾气处理处理&酸酸H2OH2O汽提汽提(2)(2)FeedGasFromFeedGasFromGasTerminalGasTerminalStationStation 来自末站的原来自末站的原料气料气WetTreatedGasWetTreatedGas 处理湿气处理湿气AcidGasAcidGas酸气酸气AcidGasAcidGas酸气酸气AcidGasAcidGas酸气酸气Sal
18、esGastoGridSalesGastoGrid商品气至管网商品气至管网ProductSulfurtoStorageProductSulfurtoStorage 硫磺产品储存硫磺产品储存VenttoAtm.VenttoAtm.VenttoAtm.VenttoAtm.AcidGasAcidGas酸气酸气15脱水目的Purpose采用不同工艺脱除天然气中水份,使其达到商品天然气管输标准中水露点。Toremovewaterfromgasbydifferentmethodstoensurethegasiswithindewpointspecificationforsalesgaspipelinetr
19、ansportation.脱水工艺方法(本厂使用TEG(三甘醇)脱水TheplantusesTEGfordehydration.OH),在结构上与水相似,甘醇的羟基与水分子可以形成氢键,由于缔合分子的键长很长,键能小,因此缔合分子是可逆的,并且可在低于甘醇沸点,高于水的沸点温度下再生提纯以供循环使用。Dehydration脱水nCritical Equipment Table TEGAbsorberProductGasK.O.DrumTEGFlashDrumBufferContainerTEGRecoveryTankOffGasK.O.DrumTEGReserveTankFuelGasBuff
20、erDrumTEGCoolerRichTEGHeaterLean/RichTEGHeatExchangern关关键设备列表列表TEG吸收塔产品气分离器TEG闪蒸罐缓冲罐TEG回收罐废气分液罐TEG储罐燃气缓冲罐TEG冷却器富液加热盘管TEG贫/富液换热器18Dehydration脱水n关关键设备列表列表TEG重沸器TEG预过滤器活性炭过滤器TEG后过滤器TEG贫液循环泵TEG回收泵TEG补充泵TEG回收总管燃气/商业气计量系统火炬nCritical Equipment Table TEGReboilerTEGPre-FilterActivatedCarbonFilterTEGTrimFilte
21、rLeanTEGCirculationPumpTEGRecoveryPumpTEGMake-upPumpTEGRecoveryHeaderFuel/CommercialGasMeteringSystemFlaresESDNarrativeReference19Dehydration脱水nCritical Equipment Table TEGAbsorberProductGasK.O.DrumTEGFlashDrumBufferContainerTEGRecoveryTankOffGasK.O.DrumTEGReserveTankFuelGasBufferDrumTEGCoolerRichTE
22、GHeaterLean/RichTEGHeatExchangern关关键设备列表列表TEG吸收塔产品气分离器TEG闪蒸罐缓冲罐TEG回收罐废气分液罐TEG储罐燃气缓冲罐TEG冷却器富液加热盘管TEG贫/富液换热器20TEG Dehydration Unit(one per train)三甘醇脱水装置(一列一三甘醇脱水装置(一列一套)套)K.O.Drum 产品气气液分离罐Flash Drum闪蒸罐TEGAbsorber 吸收塔Reboiler重沸器Wet Treated Gas处理湿气Productgas产品气Flash gas to fuel gas system 到燃料气系统的闪蒸气 Off
23、 gas toIncinerator 不合格气体到灼烧炉Lean-Rich exchanger 贫富液交换器TEGPumpTEG泵Buffer tank 缓冲罐MP steam 中压蒸气Stripping gas 汽提气LeanTEG贫液RichTEG富液21ENVIRONMENTFOCUS环保关注点液体污染:TEG溶液泄漏、化学药剂泄Liquidpollution:TEGleakage,chemicalleakage热辐射:换热器、重沸器、蒸汽泄漏HeatRadiation:heatexchanger,re-boilerandsteamleakage噪声污染:管线噪声、机械噪声Noisepo
24、llution:ductnoise,mechanicalnoise硫磺回收硫磺回收单元元Sulfur Recovery Unit(SRU)23Gas Plant overviewSulfur Sulfur Removal Removal UnitUnit 脱硫脱硫装置装置(2)(2)Tail Gas Treatment&Tail Gas Treatment&Sour H2O Stripping Sour H2O Stripping 尾气尾气处理处理&酸酸H2OH2O汽提汽提(1)(1)Sulfur Sulfur Recovery Recovery UnitUnit硫磺回收硫磺回收装置装置(1)
25、(1)Sulfur Sulfur Removal Removal Unit Unit 脱硫脱硫装置装置(1)(1)Commercial Metering StationCommercial Metering Station商业计量站商业计量站Dehydration Dehydration 三甘醇脱水三甘醇脱水Liquid Sulfur Liquid Sulfur Storage TanksStorage Tanks液硫储罐液硫储罐IncineratorIncinerator 灼烧炉灼烧炉Sulfur Sulfur FormingForming 硫硫成型成型IncineratorIncinera
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