《考研资料》2003年大连理工大学物理化学考研试题.pdf

《《考研资料》2003年大连理工大学物理化学考研试题.pdf》由会员分享，可在线阅读，更多相关《《考研资料》2003年大连理工大学物理化学考研试题.pdf（9页珍藏版）》请在淘文阁 - 分享文档赚钱的网站上搜索。

1、?http:/ !#$%&()!#$%&()!#$%&()!#$%&()*+,*+-.)/*+,*+-.)/*+,*+-.)/*+,*+-.)/01234561789:;Q?AB:;C 5627DEFGHIJK:0LMNO:;PQIR=S:;TUVBW0AXYZEFIJIRKNO:;TUVBWC 5637H2(g)O2(g)_89abcdefg=cdEFVH0=U0=p?K?6 7 8 9 10 11 12?13!#$%f&%14()*15BET+,-.+,/01234516298615 K789:;?AO2?2CO2?BrmG?CD51462 EFGHIJKLMNOPJKGHQR STUVO

2、PJKWXYZhttp:/ kJmol-17mollfghijklmnopqrstumvwxyz|xwwxyzzwxy3fsxrAvijopynbTrAprAruvmbTrAprArAbTbTrApAprAABbTbTrApAprAA CbTbTrApAprAA DbTbTrApAprAA 4298 Krn001 molkg1vr|AKCBCaCCLaCDZnSO4 5rxv|As gl sBs gl sCs gl sDg sl g 6298 KqvvNaOHNaCrNa+v1t2tvnA1t2tB1t2tC1t2tD 7OWsv|ABfC http:/ 8?ABCD9!#$%&()*+,-A

3、&().&(/0)1&(2)3%()4%(/0)1%(2)B&().&(/0)1&(2)3%()4%(/0)5%(2)C&().&(/0)5&(2)3%().%(/0)5%(2)D&().&(/0)1&(2)3%().%(/0)1%(2)6789:;?CH3C6H5ABCDEFGH1I383J2 KKLJ5 p?CH3C6H5ABCDEFGH2MNCH3C6H5ABHOPQRSCT2U1VWXYCaCO3ZBCBaCO3ZBCBaOZBCCO2AB_abCcdefgCVChijgFVWkYl298J15 KCmnLJ001 molkg-1NaCopLJ002 molkg-1Na2SO4qrst

4、uqvwxyIz|NaCzmintzRqCHCq938 dm3kgyCHCq13104 Paq825 dm3kgqbzqsA|quA|zB|C|298 K90 kPaBC? !#$http:/%&()*?101+325 kPa?A,B-.?/0,)1234/567 8)9-.:x8A9;?A?BCDEFGHIJ:B?KLMDNHOFPQRS?=TS:B?KLMD8U9VWxB;0+85?AXBYZSH?_O?OU*0X)a8b9ABcVMde-./?xB;0+fg1+0hijkQlmnopqxBr0s6twBr0s148uvw xyz|tvxyz|tvtvy 相区相态和成分条件自由度 f相区相

5、态和成分条件自由度 fDEFB A 0.6 0.8 0.2 0.4-70 100 80 90 1.0 xB t/p=p?tB tA-15A-B t/t a t/A B D E F a J K p=tB tA 0 0.2 0.4 0.6 0.8 1.0 A2B http:/ aaAB20724438 kgaw0072kgAl300 K?5000 kPa?4000 kJmol-1?mol Al300 K100 kPa?UHSAG2 kg?K?O2N2 O2N2!#$%&O2N22179()*+,25-./01Zn2345ZnO2345OH-12a607145HgO2345Hg2l489:;?79A

6、;B=?79C;01?79D;0180EF7GHI25-./fmG?9ZnOJs;6K31873 kJmol-1LfmG?9HgOJs;6K58774 kJmol-1DMNOP?QRBRCYRZ8?STUV?8WXYZ/UV?8O_QRB11,k E D /D11,kEQRB D22,k E FRZ /FRC33,k E YRZabcV?def/ghijklmnopqYdcdt=rsijtuvwx yz|http:/ ijvwxkaEAkw3533 K30762 Jmol-1rBkw3837 K31999Jmol-1ABkk101325 kPa3731KrgskxAryBmnop()()TVU

7、pTpVT=oppVanRTakr()0TUV=krsgkkrkmnxkkkmnxkkkC32R?!#?$%&()*$?+,-?.?/?012?345678?92:;7?AAAA BBBB CCCC DDDD EEEEFFFFFFFFGHIJKLDMNOPQDRSGHIJKLDMNOPQDRSGHIJKLDMNOPQDRSGHIJKLDMNOPQDRS TBUDVTBUDWXSYZRTBUDVTBUDWXSYZRTBUDVTBUDWXSYZRTBUDVTBUDWXSYZR _ 1a2b3a4b5b6a7b8b9a10b11b12a13a14a15b mnhiefop qrstmnhiuvwxh

8、ttp:/ yz|1C 2C 3D 4A 5B 6C 7A 8D 9Bz12 208 Jmol-1 2 3 3 0007 molkg-1 0907 430 min 5p4/R 654a10-4 Pa-1 7pVnRTvapH8 0203 z 7060 xB07B f f l(AB)2 s(A2B)sa(AB)1 l(AB)s(A2B)1 s(A2B)s(A)1 l(AB)sa(AB)1 DEF s(A2B)1E(AB)s(A)0 sa(AB)2 A2B0351 z375 kJ40 kJ1276 JK-1075 kJ175 kJ 8902 kJZn2OHZnOH2O2e HgOH2O2eHg2O

9、H HgOZnZnOHg(ZnO,s)(Hg,l)ln(HgO,s)(Zn,s)MFRTaaEEEzFaa=? http:/(ZnO,s)(HgO,s)rmfmfmGGG=?3185874 kJmol,2595601.345V2 97485rmM FGEVzF=?2 11/k kkcAcB211EEE+0254 0562 dUTdSpdV=?dV?TTUSTpTV=?TVSpVT=?TUT VpTTppVanRT?VPnRTVa=0TVUPTpppTT=?!#$%&()*+?,-.?Z!NqN/22,ln(/!)ln()NVV NqNqUkTNkTTT=0)qqtqrqv12.34567?89:7$;7qqt22 mkTh32V/2ln()VqUNkTT=?Um3RT2Cv,m?3R2 ABCDEFGHIJKLMENGOPQRMESGTUVWXYZMEGQO _ijdeabkl mnopijdeqrsthttp:/