纳米碳材料非金属催化的研究进展.pdf

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1、?available?at?journal?homepage:? acidQuinoneKetoneEtherPhenolLactamPyrroleAmideAmineQuaternaryCarboxylicanhydridePyridineoxidePyridineFig.?1.?Table?1?x?020406080100 Yield(%)CNTCNFOnion-like CarbonFe-K-Ce-Mo-MgFe-K-Ce-Mg-Ca-MoFig.?2.?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?

2、RRH2OO2?Fig.?3.?02040600.00.20.40.60.81.0Yield or selectivityTime on stream(h)SelectivityYield(a)Yield,nanodiamondSelectivity,nanodiamondYield,commercial catalystSelectivity,commercial catalystEtherKetoneCarboxylic acidHydroxylC(sp3)C(sp2)OHN(b)Fig.?4.?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalys

3、is?34?(2013)?508523?sp?n?sp?sp?sp?3.2.?Liquid?phase?reactions?Fig.?5.?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?3.3.?Electrocatalytic?oxygen?reduction?reactions?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?N?N?N?3.4.?Photocatalytic?reactions?-1.2-0.8-0.

4、40.0 E/V vs Ag/AgCl(e)0.3mA0.3mA132(d)(e)?Fig.?6.?Fig.?7.?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?4.?Macro?shaping?of?nanocarbon?materials?Fig.?8.?Table?2?OHR1R2OR1R2light,trifluorotolueneg-C3N4,O2(8 bar),100 oC?t?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)

5、?508523?5.?Conclusion?and?outlook?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?References?Chin?J?Org?Chem?J?Am?Chem?Soc?Angew?Chem,?Int?Ed?ChemSusChem?Catal?Today?Angew?Chem,?Int?Ed?Angew?Chem,?Int?Ed?Appl?Catal?A?J?Catal?Microporous?Mesoporous?Mater?J?Nanosci?Nanotech?Catal?To

6、day?J?Phys?Chem?Lett?Chem?Mater?Science?Angew?Chem?Int?Ed?Appl?Catal?A?Catal?Today?Angew?Chem,?Int?Ed?Carbon?Chem?CatChem?Catal?Commun?Catal?Today?J?Chem?Phys?Carbon?J?Catal?020040060080010000.00.20.40.60.81.0Conv.&selec.Time on stream(min)Selectivity Conversion Yield(b)020040060080010000.00.20.40.6

7、0.81.0 Selectivity Conversion YieldConv.&selec.Time on stream(min)(c)(a)?Fig.?9.?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?Angew?Chem,?Int?Ed?Angew?Chem,?Int?Ed?Angew?Chem,?Int?Ed?Top?Catal?Angew?Chem?Int?Ed?Appl?Catal?A?J?Mol?Catal?A?Angew?Chem,?Int?Ed?Carbon?J?Solid?State?

8、Chem?Angew?Chem,?Int?Ed?Carbon?Appl?Catal?B?Chem?Commun?Chem?Mater?Chem?Com?mun?Appl?Catal?A?Adv?Synth?Catal?Org?Biomol?Chem?Tetrahedron?Tetrahedron?Lett?Chem?Commun?Molecules?Polym?Chem?Chem?Sci?Angew?Chem?Int?Ed?Nature?Commun?Angew?Chem,?Int?Ed?Chem?Commun?New?J?Chem?Catal?Sci?Technol?Angew?Chem?I

9、nt?Ed?Angew?Chem?Int?Ed?Chem?Sci?Appl?Catal?B?Science?Nanotechnol?J?Am?Chem?Soc?Top?Catal?Catal?Lett?Angew?Chem?Int?Ed?Small?J?Phys?Chem?B?J?Catal?Catal?Lett?ACS?Nano?Surf?Sci?Carbon?J?Mater?Chem?Angew?Chem?Int?Ed?Electrochim?Acta?Graphical?Abstract?Chin.?J.?Catal.?Research?progress?in?metal?free?ca

10、rbon?based?catalysts?Institute?of?Metal?Research,?Chinese?Academy?of?Sciences;?National?Institute?of?Clean?and?Low?Carbon?Energy?Curving of graphitic structure in the nanometer scale Nanographite structureMesoporousCarbonC60NanodiamondGrapheneSWCNT?Electron DelocalizationStructural Defects?SUN?Xiaoy

11、an?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?Nat?Mater?Angew?Chem?Int?Ed?Angew?Chem?Int?Ed?J?Am?Chem?Soc?J?Mater?Chem?Adv?Mater?Chem?Commun?Carbon?J?Mater?Chem?Angew?Chem?Int?Ed?Angew?Chem?Int?Ed?ChemSusChem?a,?a,b,?a,*a?(?)?,?110016 b?,?102211?:?.?,?.?.?,?,?.?:?;?;?:2012-11-10.?:2013-0

12、1-06.?:2013-03-20.*?.?:(024)83970029;?:(024)83970019;?:?:?(21133010,21103203,50921004);?(973?,2011CBA00504);?.?Elsevier?ScienceDirect?(http:/ oC?,?,?.?,?,?(?2)813.?,?,?14.2008?,?15?,?P?100200 oC.?,?,?;?,?CO?CO2,?.?,?,?,?,?16.?.Pereira?17?,?.?,?Mars-van-Kreverlan?,?.?1820?,?X?,?.?,?Langmuir-Hinshelwo

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15、.2010?,?/?,?,?,?55.?,?,?(?60%400%).Loh?56?,?;?,?98%?5%?.?mpg-C3N45759?,?Friedel-Crafts?.?,mpg-C3N4?,?Knoevenagel?60.?61?,?,?mpg-C3N4?,?,?.?C3N4?62;?,?100%(?5.3%).?C3N4?(?100%)?,?63.?SUN?Xiaoyan?et?al.?/?Chinese?Journal?of?Catalysis?34?(2013)?508523?3.3.?(oxygen reduction reaction(ORR)?.?,?Pt?CO?,?.?

16、,?,?,?13,64,65.?,?5?.?,?,?64,66.?:?,?,?;?(NH3)?,?.?67?68.?,?,?ORR?.2006?,?69?(1?106?)?,?ORR?.Liu?70?(NOMGAs),?ORR?Pt-C?,?.Gong?65(?6)?(VA-NCNTs),?,?ORR?,?Pt?,?CO?.?.?.?,?71(?7),?.?,?7274.?,?ORR?70,75.?,?,?O2?76,77.?,?,?,?.?,?,?78.?,Mullen?79?(G-CN Nanosheets),?,?ORR?,?Pt-C?.?,?.Ozaki?80?0.5 mol?,?.3

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