三星表带材料-TPSIV介绍.pdf

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1、We Compound Your Creations TPSIV 介绍介绍 客户经理：刘荣榕 E-Mail： We Compound Your Creations Content Dow Corning and Multibase TPSIV 是什么材料 TPSIV 性能 TPSIV 应用 We Compound Your Creations Dow Corning and Multibase 有机硅技术的全球领导者 陶氏化学和康宁玻璃合资成立.7,000 多种产品，服务 25,000 多个客户 全球有约10,000名员工 100%subsidiary since 2002 全球性的热塑性材料

2、改性公司全球性的热塑性材料改性公司 We Compound Your Creations Multibase 产品目录产品目录 产品系列产品系列 材料描述材料描述 Multiflex 热塑性弹性体 Different polymer base:SEBS,SBS,polyolefins or other engineering polymers.Multipro 矿物填充改性聚烯烃 Customized rigid polyolefins with different additives.Multibatch 高填充聚烯烃母粒 Containing up to 75%of mineral fil

3、lers intended for dilution in virgin polyolefins.TPSiV 热塑性硫化硅橡胶 Our unique patented technology without plasticizer combining the benefits of silicone and thermoplastics SiE 以硅树脂为载体的热塑性弹性体 Silicone enhanced thermoplastic elastomers Siloxane Masterbatch 硅酮母粒(LDPE,LLDPE,HDPE,PP)We Compound Your Creatio

4、ns 什什么是么是 TPSiV?5 Thermoplastic Silicone Vulcanizate made by Compounding step (TPSiV)(13 patents)Si-Rubber Silky feel Low CoF Heat resistance Chemical resistance Eco TPU Flexibility Anti-abrasion Good processing Good bonding property Colorability Si-Rubber cross-linked particles TPU(or other Thermop

5、lastic)TPSiV TPU-based =Eco Reaction No Emission +Black Gray SEM Photo of TPSiV 热塑性硫化硅胶 We Compound Your Creations 为何选择为何选择 TPSiV?丝滑的丝滑的触感触感 Silky feel,no sticky We Compound Your Creations Hardness shore A TPSiV-硬度范围及丝滑的触感硬度范围及丝滑的触感 90-A 80-A 70-A 60-A Sticky Dry Silky TPE TPU Coated LSR Feeling Sof

6、tness Thermoplastic transformation process Other transformation processes Plasticised materials PU coating TPSiV We Compound Your Creations 颜色多样性颜色多样性 TPSiV 可以染成多种颜色，但高光泽的颜色需要借助表面涂层实现可以染成多种颜色，但高光泽的颜色需要借助表面涂层实现 We Compound Your Creations 耐磨性耐磨性 TPSiV gives superior abrasion resistance and product pro

7、tection TPSiV 70A TPSIV 65A TPSIV 60A Bondable TPV Bondable TPU Alloy 0 20 40 60 80 100 120 140 Weight Loss(mg)(Tabor,weight loss)TPU 85A We Compound Your Creations 抗化学性抗化学性 沾污沾污 食品食品:可口可乐可口可乐 调味番茄酱 醋 蛋黄酱 芥末 橄榄油 化妆品化妆品:防晒霜 发胶 卸妆水 唇膏 爽肤水 人体人体:汗 皮脂 工业工业:防冻剂防冻剂 清洁剂 喷剂 杀虫剂 酒精 油酸 Recommended for all colo

8、urs Recommended only for short term exposure/dark colours Not recommended 168 hrs 浸泡测试，以浸泡测试，以65A 脂肪族脂肪族 TPU 基材的基材的 TPSiV为为样品样品 Degradation data We Compound Your Creations 抗化学性抗化学性 降解降解 食品食品:可口可乐可口可乐 调味番茄酱 醋 蛋黄酱 芥末 橄榄油 化妆品化妆品:防晒霜 发胶 卸妆水 NA 唇膏 NA 爽肤水 人体人体:汗 皮脂 NA 工业工业:防冻剂防冻剂 清洁剂 喷剂 杀虫剂 酒精 油酸 Recommen

9、ded for all colours Recommended only for short term exposure/dark colours Not recommended 168 hrs 浸泡测试，以浸泡测试，以 65A 脂肪族脂肪族 TPU 基材的基材的TPSiV为样品为样品 We Compound Your Creations Bond with many plastics Hardness 0 10 20 30 40 50 60 70 80 90A /10 20 30 40D PC,ABS,PBT,ASA TEA TPU Modified TPU TPSiV PP,PE TPE

10、Choc TPV TPO TPSiV PA,PPA TPSiV Co-polyesters(Arnitel,Hytrel)PA based TPEs We Compound Your Creations 机械强度机械强度 20%40%60%80%100%120%压缩永久变形压缩永久变形(70 C)压缩永久变形压缩永久变形(23 C)拉伸断裂强度拉伸断裂强度(Mpa)与与PC的包覆强度的包覆强度 耐磨性耐磨性 撕裂强度(kN/m)对比测试硬度对比测试硬度:60 A TPSiV 包胶TPV 包胶 TPU Alloy We Compound Your Creations 抗抗UV性性 TPSiV 6

11、0A TPV TPU Alloy TPSiV 可以提供较好的抗可以提供较好的抗UV性性 E:1.84 4.24 17.68 TPU E:25.87(500 hours at 0.5 W/m2 340 nm)We Compound Your Creations 耐热性耐热性(in air at 120C for 1000 hours)TPSiV 可以提供较好的耐热性和性能保持能力可以提供较好的耐热性和性能保持能力 TPSiV 60A TPV TPU Alloy TPU We Compound Your Creations 压缩永久变形压缩永久变形 TPSiV gives improved com

12、pression set,especially at high temperatures 0 10 20 30 40 50 60 70 80 90 100 Compression Set(%)23C 70C TPSiV 70A TPSIV 65A TPSIV 60A Bondable TPV Bondable TPU Alloy TPU We Compound Your Creations TPSiV应用开发应用开发 抗菌抗菌 TPSiV 选择规格:TPSiV 65A 卓越的抗UV性 卓越的PC/ABS包覆强度 卓越的耐磨性 UL 94 HB at 0.86 to 3.0 mm 采用独特的抗菌

13、技术，提供永久的卫生解决方案，通过接触即可获得杀菌效果 实验数据参考如下 We Compound Your Creations 抗菌规格抗菌规格 TPSiV 65A AB Property Units TPSiV 65A Standard TPSIV 65A AB 硬度 Shore A 67 68 拉伸强度 MPa 6.4 7.4 断裂伸长率%540 600 撕裂强度 kN/mm 40 43 抗菌 1个小时后可以杀死超过99.99%的大肠杆菌和and 耐甲氧西林金黄色葡萄球菌!对机械性能和加工性无明显影响 We Compound Your Creations SampleAvg Suvivin

14、g/mLAvg Kill/mLLog Kill%Reduction Log Reduction NBlank7.80E+046.02E+055.7888.53%0.941Control2.80E+054.00E+055.6058.82%0.3910.5%HM41002.94E+046.51E+055.8195.68%1.3611.0%HM41000.00E+006.80E+055.8399.99%4.001Thermoplastic Silicone Vulcanizate vs E.coli-1 Hour Shake Test99.99%95.68%58.82%1.360.394.000.0

15、0%25.00%50.00%75.00%100.00%Control0.5%HM41001.0%HM4100%Reduction0.001.002.003.004.00Log Reduction%ReductionLog Reductiont0=6.80E5 E.coli CFU/mL*Samples cleaned with EtOH prior to testing*0.01%Q2-5211 added to inoculum*1in2 in 4mL of inoculum*Samples diluted in D/E Neutralizing BrothDWT157-1Thermopla

16、stic Silicone Vulcanizate vs E.coli 1 小时震动测试小时震动测试 测试报告测试报告 We Compound Your Creations Thermoplastic Silicone Vulcanizate vs E.coli 24 小时震动测试小时震动测试 SampleAvg Suviving/mLAvg Kill/mLLog Kill%Reduction Log ReductionSt DevSt Dev(%)NBlank1.37E+055.43E+055.7379.80%0.697.34E+0410.79%3Control2.49E+054.31E+0

17、55.6363.43%0.441.50E+042.21%30.5%HM41000.00E+006.80E+055.8399.99%4.000.00E+000.00%31.0%HM41000.00E+006.80E+055.8399.99%4.000.00E+000.00%3TPSiV vs E.coli-24 Hour Shake Test99.99%99.99%63.43%4.000.444.000.00%25.00%50.00%75.00%100.00%Control0.5%HM41001.0%HM4100%Reduction0.001.002.003.004.00Log Reductio

18、n%ReductionLog Reductiont0=6.80E5 E.coli CFU/mL*Samples cleaned with EtOH prior to testing*0.01%Q2-5211 added to inoculum*1in2 in 4mL of inoculum*Samples diluted in D/E Neutralizing BrothDWT157-1测试报告测试报告 1-24 hrs 100%的大肠杆菌被杀死的大肠杆菌被杀死 We Compound Your Creations 测试报告测试报告 We Compound Your Creations Las

19、er-marking additives efficiency TPSiV 镭雕镭雕 Through compounding with Lazerflair or Micabs,TPSiV can do laser marking.Lazerflair&Micabs are Registered Mark from by Merck Chemical International We Compound Your Creations TPSiV 融聚各种特性于一身融聚各种特性于一身 Skin-touch feeling Plasticizer free Good properties combi

20、nation 可与多种塑料二次注塑可与多种塑料二次注塑 硅胶降低了摩擦系数，硅胶降低了摩擦系数，提提高了耐磨性高了耐磨性 抗抗UV 耐耐热性得到提高热性得到提高 耐化学性好耐化学性好 相相比比TPU，不容易出“飞边”，适合薄壁设计加工，不容易出“飞边”，适合薄壁设计加工 不含塑化剂，不会出现不含塑化剂，不会出现TPE，TPU等材料的“析蜡”现象等材料的“析蜡”现象 不不容容易发粘，粘灰易发粘，粘灰 硬度范围硬度范围:50A80A，回弹性好，比一般，回弹性好，比一般TPU软软 注塑加工，无需二次处理（如喷手感油）即有丝滑的触感注塑加工，无需二次处理（如喷手感油）即有丝滑的触感 TPSIV=热塑性

21、基材热塑性基材+热固性硅胶热固性硅胶 We Compound Your Creations TPSIV 适合什么应用？适合什么应用？1.注塑加工（单射或双射），手感要求较高，耐磨，耐注塑加工（单射或双射），手感要求较高，耐磨，耐UV 耳机 手机/平板电脑保护套 手机外壳（代替PU皮革漆）手表腕带（单射）便携式测量仪器的把手 眼镜（与TR90二次包胶）助听器耳蜗 便携式音响 婴儿用品（喂食勺头，水杯把手等）2.注塑加工注塑加工，防水等级要求高（，防水等级要求高（IP*7）,高回弹性，较高回弹性，较软的软的硬硬度度 工业手机防水密封圈（代替TPU或者LIMS）GPS 导航仪 皮肤接触：耳朵、手掌、

22、手指、手腕皮肤接触：耳朵、手掌、手指、手腕 We Compound Your Creations TPSiV 应应用用 We Compound Your Creations Disclosure and legal information LIMITED WARRANTY INFORMATION-PLEASE READ CAREFULLY The information contained herein is offered in good faith and is believed to be accurate.However,because conditions and methods o

23、f use of our products are beyond our control,this information should not be used in substitution for customers tests to ensure that Multibases products are safe,effective,and fully satisfactory for the intended end use.Suggestions of use shall not be taken as inducements to infringe on any patent.Mu

24、ltibases sole warranty is that the product will meet the Multibase sales specifications in effect at the time of shipment.The exclusive remedy for breach of such warranty is limited to refund of purchase price or replacement of any product shown to be other than as warranted.MULTIBASE SPECIFICALLY D

25、ISCLAIMS ANY OTHER EXPRESS OR IMPLIED WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE OR MERCHANTABILITY.MULTIBASE DISCLAIMS LIABILITY FOR ANY INCIDENTAL OR CONSEQUENTIAL DAMAGES.TPSiV is a Registered Mark from Dow Corning Corporation.Multiflex is a Trade Mark of Multibase.Multibase is a Registered Mark of Multibase Company