新版氯代异丁烷安全技术说明书英文.pdf

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1、SAFETY DATA SHEETSSAFETY DATA SHEETSAccordingAccording toto GloballyGlobally HarmonizedHarmonized SystemSystem ofof ClassificationClassification andand LabellingLabelling ofof ChemicalsChemicals(GHS)(GHS)-Sixth revised edition-Sixth revised editionVersion:1.0Creation Date:Aug 14,2017Revision Date:Au

2、g 14,20171.Identification1.Identification1.1GHS Product identifier1.1GHS Product identifierProduct nameProduct name1-Chloro-2-Methylpropane1.2Other means of identification1.2Other means of identificationProduct numberProduct numberOther namesOther names-1-Chloro-2-methylpropane1.3Recommended use of

3、the chemical and restrictions on use1.3Recommended use of the chemical and restrictions on useIdentified usesIdentified usesUses advised againstUses advised against1.4Suppliers details1.4Suppliers detailsCompanyCompanyAddressAddressTelephoneTelephoneFaxFax1.5Emergency phone number1.5Emergency phone

4、numberEmergency phone numberEmergency phone number+86-400-6021-666Service hoursService hoursMonday to Friday,9am-5pm(Standard time zone:UTC/GMT+8hours).2.Hazard identification2.Hazard identification2.1Classification of the substance or mixture2.1Classification of the substance or mixtureFlammable li

5、quids,Category 2For industry use only.no data availableMOLBASE(Shanghai)Biotechnology Co.,Ltd.Floor 4&5,Building 12,No.1001 North Qinzhou Road,Xuhui District,Shanghai,China+86(21)64956998+86(21)543651662.2GHS label elements,including precautionary statements2.2GHS label elements,including precaution

6、ary statementsPictogram(s)Pictogram(s)Signal wordSignal wordHazard statement(s)Hazard statement(s)PrecautionaryPrecautionarystatement(s)statement(s)PreventionPreventionDangerH225 Highly flammable liquid and vapourP210 Keep away from heat,hot surfaces,sparks,open flames andother ignition sources.No s

7、moking.P233 Keep container tightly closed.P240 Ground and bond container and receiving equipment.P241 Use explosion-proof electrical/ventilating/lighting/.equipment.P242 Use non-sparking tools.P243 Take action to prevent static discharges.P280 Wear protective gloves/protective clothing/eyeprotection

8、/face protection.ResponseResponseP303+P361+P353 IF ON SKIN(or hair):Take off immediately allcontaminated clothing.Rinse skin with water or shower.P370+P378 In case of fire:Use.to extinguish.P403+P235 Store in a well-ventilated place.Keep cool.P501 Dispose of contents/container to.StorageStorageDispo

9、salDisposal2.3Other hazards which do not result in classification2.3Other hazards which do not result in classificationnone3.Composition/information on ingredients3.Composition/information on ingredients3.1Substances3.1SubstancesCASCASECECConcentrationConcentrationnumbernumbernumbernumber1-Chloro-2-

10、Methylpropane 1-Chloro-2-Methylpropane 513-36-0none100%Chemical nameChemical nameCommon names and synonymsCommon names and synonyms4.First-aid measures4.First-aid measures4.1Description of necessary first-aid measures4.1Description of necessary first-aid measuresGeneral adviceGeneral adviceConsult a

11、 physician.Show this safety data sheet to the doctor in attendance.If inhaledIf inhaledFresh air,rest.In case of skin contactIn case of skin contactRemove contaminated clothes.Rinse and then wash skin with water and soap.In case of eye contactIn case of eye contactFirst rinse with plenty of water fo

12、r several minutes(remove contact lenses if easily possible),then refer for medical attention.If swallowedIf swallowedRinse mouth.Give one or two glasses of water to drink.Refer for medical attention.4.2Most important symptoms/effects,acute and delayed4.2Most important symptoms/effects,acute and dela

13、yedno data available4.3Indication4.3Indication ofof immediateimmediate medicalmedical attentionattention andand specialspecial treatmenttreatment needed,needed,ifif necessarynecessaryno data available5.Fire-fighting measures5.Fire-fighting measures5.1Extinguishing media5.1Extinguishing mediaSuitable

14、 extinguishing mediaSuitable extinguishing mediaUse powder,AFFF,foam,carbon dioxide.5.2Specific hazards arising from the chemical5.2Specific hazards arising from the chemicalno data available5.3Special protective actions for fire-fighters5.3Special protective actions for fire-fightersWear self-conta

15、ined breathing apparatus for firefighting if necessary.6.Accidental release measures6.Accidental release measures6.1Personal precautions,protective equipment and emergency procedures6.1Personal precautions,protective equipment and emergency proceduresUse personal protective equipment.Avoid dust form

16、ation.Avoid breathing vapours,mist or gas.Ensure adequate ventilation.Evacuate personnel to safe areas.Avoid breathing dust.For personal protection see section 8.6.2Environmental precautions6.2Environmental precautionsPersonal protection:filter respirator for organic gases and vapours adapted to the

17、 airborne concentration of the substance.Do NOTwash away into sewer.Collect leaking and spilled liquid in sealable containers as far as possible.Absorb remaining liquid in sandor inert absorbent.Then store and dispose of according to local regulations.6.3Methods and materials for containment and cle

18、aning up6.3Methods and materials for containment and cleaning upPick up and arrange disposal.Sweep up and shovel.Keep in suitable,closed containers for disposal.7.Handling and storage7.Handling and storage7.1Precautions for safe handling7.1Precautions for safe handlingAvoid contact with skin and eye

19、s.Avoid formation of dust and aerosols.Avoid exposure-obtain special instructions beforeuse.Provide appropriate exhaust ventilation at places where dust is formed.For precautions see section 2.2.7.2Conditions for safe storage,including any incompatibilities7.2Conditions for safe storage,including an

20、y incompatibilitiesFireproof.Separated from powdered metals and strong oxidants.8.Exposure controls/personal protection8.Exposure controls/personal protection8.1Control parameters8.1Control parametersOccupational Exposure limit valuesOccupational Exposure limit valuesno data availableBiological limi

21、t valuesBiological limit valuesno data available8.2Appropriate engineering controls8.2Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice.Wash hands before breaks and at the end of workday.8.3Individual protection measures,such as personal protective

22、 equipment(PPE)8.3Individual protection measures,such as personal protective equipment(PPE)Eye/face protectionEye/face protectionSafety glasses with side-shields conforming to EN166.Use equipment for eye protection tested and approved under appropriategovernment standards such as NIOSH(US)or EN 166(

23、EU).Skin protectionSkin protectionWear impervious clothing.The type of protective equipment must be selected according to the concentration and amount of thedangerous substance at the specific workplace.Handle with gloves.Gloves must be inspected prior to use.Use proper gloveremoval technique(withou

24、t touching gloves outer surface)to avoid skin contact with this product.Dispose of contaminated glovesafter use in accordance with applicable laws and good laboratory practices.Wash and dry hands.The selected protective gloveshave to satisfy the specifications of EU Directive 89/686/EEC and the stan

25、dard EN 374 derived from it.Respiratory protectionRespiratory protectionWear dust mask when handling large quantities.Thermal hazardsThermal hazardsno data available9.Physical and chemical properties9.Physical and chemical propertiesPhysical statePhysical stateclear colourless liquidColourColourno d

26、ata availableOdourOdourno data availableMelting point/freezingMelting point/freezing-131CpointpointBoiling point or initialBoiling point or initial68-69Cboilingboiling pointpoint andand boilingboilingrangerangeFlammabilityFlammabilityHighly flammable.Gives off irritating or toxic fumes(orgases)in a

27、fire.LowerLower andand upperupper explosionexplosionno data availablelimit/flammabilitylimit/flammabilitylimitlimitFlash pointFlash point-10CAuto-ignitionAuto-ignitionno data availabletemperaturetemperatureDecompositionDecompositionno data availabletemperaturetemperaturepHpHno data availableKinemati

28、c viscosityKinematic viscosityno data availableSolubilitySolubilityIn water:28 mg/l(20 C)Partition coefficientPartition coefficientno data availablen-octanol/water(logn-octanol/water(logvalue)value)Vapour pressureVapour pressureno data availableDensity and/or relativeDensity and/or relative 0.883den

29、sitydensityRelative vapour densityRelative vapour density(air=1):3.2Particle characteristicsParticle characteristicsno data available10.Stability and reactivity10.Stability and reactivity10.1Reactivity10.1Reactivityno data available10.2Chemical stability10.2Chemical stabilityStable under recommended

30、 storage conditions.10.3Possibility of hazardous reactions10.3Possibility of hazardous reactionsThe vapour is heavier than air and may travel along the ground;distant ignition possible.As a result of flow,agitation,etc.,electrostatic charges can be generated.10.4Conditions to avoid10.4Conditions to

31、avoidno data available10.5Incompatible materials10.5Incompatible materialsno data available10.6Hazardous decomposition products10.6Hazardous decomposition productsno data available11.Toxicological information11.Toxicological informationAcute toxicityAcute toxicityOral:no data availableInhalation:no

32、data availableDermal:no data availableSkin corrosion/irritationSkin corrosion/irritationno data availableSerious eye damage/irritationSerious eye damage/irritationno data availableRespiratory or skin sensitizationRespiratory or skin sensitizationno data availableGerm cell mutagenicityGerm cell mutag

33、enicityno data availableCarcinogenicityCarcinogenicityno data availableReproductive toxicityReproductive toxicityno data availableSTOT-single exposureSTOT-single exposureno data availableSTOT-repeated exposureSTOT-repeated exposureno data availableAspiration hazardAspiration hazardno data available1

34、2.Ecological information12.Ecological information12.1Toxicity12.1ToxicityToxicity to fish:no data availableToxicity to daphnia and other aquatic invertebrates:no data availableToxicity to algae:no data availableToxicity to microorganisms:no data available12.2Persistence and degradability12.2Persiste

35、nce and degradabilityno data available12.3Bioaccumulative potential12.3Bioaccumulative potentialno data available12.4Mobility in soil12.4Mobility in soilno data available12.5Other adverse effects12.5Other adverse effectsno data available13.Disposal considerations13.Disposal considerations13.1Disposa

36、l methods13.1Disposal methodsProductProductThe material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gasscrubbing.Do not contaminate water,foodstuffs,feed or seed by storage or disposal.Do not discharge to sewer systems.Contaminated p

37、ackagingContaminated packagingContainers can be triply rinsed(or equivalent)and offered for recycling or reconditioning.Alternatively,the packaging can bepunctured to make it unusable for other purposes and then be disposed of in a sanitary landfill.Controlled incineration with fluegas scrubbing is

38、possible for combustible packaging materials.14.Transport information14.Transport information14.1UN Number14.1UN NumberADR/RID:UN112714.2UN Proper Shipping Name14.2UN Proper Shipping NameADR/RID:CHLOROBUTANESIMDG:CHLOROBUTANESIATA:CHLOROBUTANES14.3Transport hazard class(es)14.3Transport hazard class

39、(es)ADR/RID:314.4Packing group,if applicable14.4Packing group,if applicableADR/RID:II14.5Environmental hazards14.5Environmental hazardsADR/RID:no14.6Special precautions for user14.6Special precautions for userno data availableIMDG:UN1127IATA:UN1127IMDG:3IATA:3IMDG:IIIATA:IIIMDG:noIATA:no14.7Transpor

40、t in bulk according to Annex II of MARPOL 73/78 and the IBC Code14.7Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codeno data available15.Regulatory information15.Regulatory information15.1Safety,health and environmental regulations specific for the product in question15.1Safet

41、y,health and environmental regulations specific for the product in questionChemical nameChemical nameCommon names and synonymsCommon names and synonymsCAS numberCAS numberEC numberEC number1-Chloro-2-Methylpropane1-Chloro-2-Methylpropane513-36-0noneEuropeanEuropean InventoryInventory ofof ExistingEx

42、isting CommercialCommercial ChemicalChemical SubstancesSubstances(EINECS)(EINECS)Listed.EC InventoryEC InventoryListed.United States Toxic Substances Control Act(TSCA)InventoryUnited States Toxic Substances Control Act(TSCA)InventoryListed.China Catalog of Hazardous chemicals 2015China Catalog of Ha

43、zardous chemicals 2015Listed.New Zealand Inventory of Chemicals(NZIoC)New Zealand Inventory of Chemicals(NZIoC)Listed.Philippines Inventory of Chemicals and Chemical Substances(PICCS)Philippines Inventory of Chemicals and Chemical Substances(PICCS)Listed.Vietnam National Chemical InventoryVietnam Na

44、tional Chemical InventoryNot Listed.Chinese Chemical Inventory of Existing Chemical Substances(ChinaChinese Chemical Inventory of Existing Chemical Substances(ChinaListed.IECSC)IECSC)16.Other information16.Other informationInformation on revisionInformation on revisionCreation DateCreation DateRevis

45、ion DateRevision DateAbbreviations and acronymsAbbreviations and acronymsCAS:Chemical Abstracts ServiceAug 14,2017Aug 14,2017ADR:European Agreement concerning the International Carriage of Dangerous Goods by RoadRID:Regulation concerning the International Carriage of Dangerous Goods by RailIMDG:Inte

46、rnational Maritime Dangerous GoodsIATA:International Air Transportation AssociationTWA:Time Weighted AverageSTEL:Short term exposure limitLC50:Lethal Concentration 50%LD50:Lethal Dose 50%EC50:Effective Concentration 50%Disclaimer:The above information is believed to be correct but does not purport t

47、o be all inclusive and shallDisclaimer:The above information is believed to be correct but does not purport to be all inclusive and shallbe used only as a guide.The information in this document is based on the present state of our knowledge and isbe used only as a guide.The information in this docum

48、ent is based on the present state of our knowledge and isapplicable to the product with regard to appropriate safety precautions.It does not represent any guarantee ofapplicable to the product with regard to appropriate safety precautions.It does not represent any guarantee ofthe properties of the product.We as supplier shall not be held liable for any damage resulting from handlingthe properties of the product.We as supplier shall not be held liable for any damage resulting from handlingor from contact with the above product.or from contact with the above product.