金属有机框架的合成和应用优秀PPT.pptx

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1、energy crisisWe NeedRenewableenergy！Environment pollutiona material to a material to restore itrestore it！We also NeedMetal Organic Metal Organic FrameworksFrameworks（MOFsMOFs）Team membersTeam members：Qin Meng Ye Ting Song Yixuan Qin Meng Ye Ting Song Yixuan Gai Linlin Mo Jiamei Liu Yongying Gai Lin

2、lin Mo Jiamei Liu Yongying Zhou Jinling Li Qianru Sun Tian Zhou Jinling Li Qianru Sun Tian Du Yina Du Yina CONTENTSynthetic Chemistry of Materials123IntroductionSynthesis of MOFsApplication of MOFsIntroduction1Synthetic Chemistry of MaterialsIntroductionmore than 20,000 different MOFsIntroductionSyn

3、thetic Chemistry of MaterialsProperities:Properities:l l intriguing topologiesintriguing topologiesl l higher surface area higher surface area l l Designable channel and founctionalizedDesignable channel and founctionalized framworksframworksIsoreticular Metal Organic Framework(IRMOF)was fabricated

4、by Yaghi O M,realizing the transition from static microporous materials to the perfect crystaline mesoporous materials.19891995200219992004200520102006The topology theory was applied to the coordination compound by Robson R.The coordination compound with 2d structure,firstly named MOFs,was prepared

5、by Yaghi O M.MOF-5 with simple cubic structure was prepared by Yaghi O M.MIL-100 and MIL-101 materials with macroporous molecular sieve structure were synthesised by Freys team.MIL-53(X)with a superior performance in gas separation was synthesised by the Freys team.Zeolitic Imidazolate Frameworks(ZI

6、Fs)with excellent thermal and chemical stability were synthesised by Yaghi O M.The conception of diverse functional Metal-Organic Skeleton materials(MVT-MOFS)was put forward.IntroductionSynthetic Chemistry of MaterialsSynthesis2Synthesis of MOFs3Traditional Method2Layer-by-Layer Method3Microwave-ass

7、isted MethodSecond growth Method41Aqueous solution of metalorganic solvent solution of ligandmixedsolventmixedsolventofwaterandofwaterandorganicorganicTEXT TraditionalMethodLayering MethodJ.Choi,G.Gillan Edward.Inorg.Chem.2005,44,7385.Solvothermal MethodMicrowave assisted method(1)Dipole rotation(1)

8、Dipole rotation(2)Collision takes place(2)Collision takes place(2)(2)Local Local heating heating energy efficiency energy efficiencyMOF-5 Fig.1 SEM images of MOF-5 prepared under (a)conventional solvothermal synthesis and (b)microwave heating.Microwave assisted methodJ.S.Choi,W.J.Son,J.Kim and W.S.A

9、hn,Microporous Mesoporous Mater.2008,116,727731crystallinity and morphology of MOF-5 Conventional heating was used for comparison.Layer-by-Layer MethodFig.2 Layer-by-layer growth of HKUST-1 thin films on COOH-terminated support.The substrate is repeatedly immersed in solutions The substrate is repea

10、tedly immersed in solutions of Cu(OAc)of Cu(OAc)2 2 and H and H3 3BTC,with an intermediate washing BTC,with an intermediate washing between successive steps.between successive steps.C.Munuera,O.Shekhah.,H.Wang,C.Woll.,C.Ocal.Phys.Chem.Chem.Phys.2008,10,7257.TEXTseeds pre-coatedN.Stock,S.Biswas.Chem

11、Rev.2012;112(2):933-69.Seeds pre-coated:Seeds pre-coated:(1)spin-or dip-coating (3)rubbing(1)spin-or dip-coating (3)rubbing(2)direct growth (4)Layer-by-layer(LBL)growth.(2)direct growth (4)Layer-by-layer(LBL)growth.Fig.4 Comparison between direct and secondary growth methods for the preparation of M

12、OF thin films under solvothermal conditions.Secondary Growth16TEXTTEXTFig.5 DRMs assisted growth of MOF-5 on a flat surface.Fig.6 DRMs used for positioning MOF-5 on patterned supportsSecondary GrowthFunctionalization(DRMs)2-Dimension3-DimensionSelective catalytic ReductionAdvantagesAdvantagesP.Falca

13、ro.et al.Nat.Commun.,2011,2,237-244.CrystalSecondary GrowthApplication3Application of MOFsMolecular TransportY.Ikezoe,G.Washino,T.Uemura,S.Kitagawa and H.Matsui,Nat.Mater.,2012,11,10811085B.D.Gates,Q.Xu,M.Stewart,D.Ryan,C.G.Willson and G.M.Whitesides,Chem.Rev.,2005,105,11711196Large surface tensionB

14、ig porousDevicesDevicesactuators;Sensors;targeted drug injectionosmotic pumpingOpticsG.Lu and J.T.Hupp,J.Am.Chem.Soc.,2010,132,78327833C.-Y.Sun,X.-L.Wang,X.Zhang,C.Qin,P.Li,Z.-M.Su,D.-X.Zhu,G.-G.Shan,K.-Z.Shao,H.Wu and J.Li,Nat.Commun.,2013,4,2717C.-W.Kung,T.C.Wang,J.E.Mondloch,D.Fairen-Jimenez,D.M.Gardner,W.Bury,J.M.Klingsporn,J.C.Barnes,R.Van Duyne,J.F.Stoddart,M.R.Wasielewski,O.K.Farha and J.T.Hupp,Chem.Mater.,2013,25,50125017Lanthanides dopingThin film DevicesDevicesSelective gas sensorLED emitter22THANKYOU!WHY MOFs?WHY MOFs？