2024高考化学密训卷（三）-试卷含答案.pdf

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1、?1?14?2?14?H 1 C 12 N 14 O 16 K 39 Br 80 I127 Hf 178 Pb 207?1?“?”?A?19?“?”?“?”?B?C?D?2?2+46Na Fe(CN)+Fe?+26Na FeFe(CN)+2Na?A?B?-CN?:CN:?C?46Fe CN?1:1D?46Fe CN?3?A?NH2Cl?B?C?Cr?D?23CO?VSEPR?公众号【永久学堂】微信：yjxt6699?xt66?信：yj?Na FNa F2 2快速更新?3?14?4?14?4?A?1.0 mol/L NaOH?-4Al OH?3NO?3CH COO?+KB?+Hc?10110m

2、ol L?2+Mg?+K?Cl?24SO?C?10.1 mol L?2FeCl?+4NH?+K?63Fe CN?3NO?D?10.1 mol L?pH?5?3CH CHO?24SO?+Na5?A?B?4KMnO?C?2H?3?D?1 mol?3 mol NaOH?6?Andrussow?4322CH+2NH+3O=22HCN+6H O?NA?A?39.2 L?A3NB?100 mL 2 mol/L?HCN?A0.8NC?14-5.6 g CN?A0.2ND?4CH?3CH OH?31 mol CH OH?3sp?A2N7?Li?Al?Si?a pm?1?12?0?12?2?0?12?0?A.?

3、3?34?34?14?B.?Al?Si?4?C.?310 3A248 g cm(10)aN?D?Si?Li?2 pm4a8?PC?X?Y?A?2?B?X?Y?C?Y?D?1 mol X?22 mol Br?9?W?X?Y?Z?M?W?M?Y?Z?M?X?Y?A?W?X?YB?X?Z?X?C?Z?M?D?M?X?M?5?14?6?14?10?ABCD?a?b?2Fe OH?2Cl?HCl?2H O?11.?pH=4?A?B?“?1”?C?“?”?“?”?D?“?pH=4”?12?NO?NO?A?B?1 mol224 S O?NO?11.2 L2NC?+Na?D?+232422HSO+2H=S O

4、+2H O+2e?13?CO?NO?2NO g+2CO g?22N+2COgg H?22NOCOvkpp?222()()NCOvk pp?k?k?p?(?=?)?()A?kk?B?CO?NO?N2?2:2:1?0p kPa?00.9p kPa?7.5?0k=kpC?k?k?H?0D?v?v?14?33H XO?1aK?2aK?3aK?HCl?331 L 0.1 mol/L Na XO?X?公众号【永久学堂】微信：yjxt6699?N N?快速更新?7?14?8?14?33 H XO=3332333233(H XO)(H XO)(H XO)(HXO)(XO)ccccc?HCl?pOH?A?33H

5、 XO?Ka1=4.810?B?M?a2a3lglgpH2KK?C?23KH XO?D?N?pOH=7?323233(H XO)2(HXO)3(XO)=(Na)cccc?15?3AgNO?+Ag?+Ag?2%3AgNO?1 mL?22?2%?3?40%?2%3AgNO?1 mL?22?3?40%?1?_?2?1?+Ag?2?_?+Ag?3?2?NaCl?NaOH?a?b?c?_?c?3AgNO?_?4?+32Ag NH?+3Ag+2NH?AgCl s+Ag+Cl?AgCl?_?9?14?10?14?16?pH?3+Ga3+Al3+Fe2+Fe?c?0.01 mol/L?pH4.53.72.27

6、.5?c?1.010?5 mol/L?pH5.54.73.29.0?Al?Ga?3Al OH?3Ga OH?4Al OH?4Ga OH?1?“?”?Ti?2?2+Fe?“?”?“?”?0.1 mol/L?“?”?pH?“?”?3?“?”?4?“?”?2CO?5?4Na Ga OH?Ga?6?25?3Ga OH?32NHH ObK?52.0 10?3spGa OHK?30.51.0 10?323Ga OHs+NHH O aq?+44Ga OHaq+NHaq?K62.0 10?3+Ga+4OH?4Ga OH?K?17.?DVB?ABS?PS?DEB?101410102C HC H2Hg DEB D

7、VBH?1010C H1010?EVB?I?1014101221C HC HHg DEB EVBH?1012C H1012?II?1012101022C HC HHg EVB DVBH?1010C H1010?1?II?2(DVB)(H)yxvk cc?2(VB)(H)2cc(DVB)x?k?c(DVB)/(molL?1)c(2H)/(molL?1)v/(11mol Ls?)10.100.10r20.100.202r30.200.104r40.050.30?4?11mol Ls?r?2?_?DEB?公众号【永久学堂】微信：yjxt6699?t?快速更新新?11?14?12?14?DEB?_?A

8、.3 B.4 C.5 D.6?DEB?_?A.?B.?C.?3?pK?B?p?B?kPa?p0?p0?100 kPa?I?II?lnpK?1T?DEB?DVB?H?_0?“?”?“?”?pK?=_?A?100 kPa?10 mol DEB?2(H):(DEB)2:1pp?(DVB)n?1.25 mol?DEB?18.?3ABX?A?B?2+Pb?2+Sn?X?Cl?Br?I?2+Pb?I?+33CH NH?I?a nm?1?Pb?IVA?2+Pb?_?2?+33CH NH?N?_?+33CH NH_4NH?“”?“”?_?3?+33CH NH?I-?_?13?14?14?14?4?_?5?Hf

9、?4+Hf?Br?1?34?14?14?2?34?34?14?3?_?+K?_?_?gcm-3?NA?HfK?_nm?MK=39 g/mol?MHf=178 g/mol?MBr=80 g/mol?19?1?A?2?B?D?3?FH?4?GH?a?3HNO/24H SOb?2SnCl/HClc?NaOH/25C H OHd?3AgNO/3NH?5?E+IJ?6?X?B?2?5?2:2:2:1:1?公众号【永久学堂】微信：yjxt6699 9 快速速速速速速速速速速速速速速更更更更更更更更更更更更更更更更新新新新新新新新新新新新新新新新?公众号【永久学堂】微信：yjxt6699?永久学堂】微信：y

10、jxt6699 学堂】微信：yjxt6699?快速更新?1?14?2?14?1?D?A?“?”?A?B?B?C?C?D?D?D?2?D?A?7?5?A?B?-CN?:C?N:-?B?C?46Fe CN?Fe?-CN?C?N?CN?1?2?46Fe CN?12:12=1:1?C?D?D?D?3?A?A?2NH Cl?A?B?C?O?H?B?C?Cr?C?D?23CO?(422 3332?VSEPR?D?A?4?A?A?1.0 mol/L NaOH?A?B?Hc?10?10 molL?1?2+Mg?2Mg OH?2+Mg?B?C?36Fe CN?C?D?4MnO?3CH CHO?0.1 mol/L

11、?4KMnO?pH?5?3CH CHO?D?A?5?B?A?A?B?B?C?4?2?C?D?2?1?NaOH?NaOH?NaOH?1 mol?4 mol NaOH?D?B?6?C?A?Andrussow?42 mol CH?32 mol NH?23 mol O?7 mol?3?14?4?14?12NA?3NA?722.43/12 L=39.2 L?A?B?100 mL 2 mol/L?HCN?HCN?CN?-HCNCNnn?cV=0.2 mol?HCN?CN?4?100 mL 2 mol/L?HCN?0.8 NA?B?C?145.6 g CN?0.2 mol?0.2(6+7+1)=2.8 mo

12、l?0.2(8+7)=3.0 mol?145.6 g CN?0.2 NA?C?D?3CH OH?sp3?31 mol CH OH?sp3?2NA?D?C?7?D?A.?1?2?Al?3?34?34?14?A?B.?Al?1186482?Si?4?Si?Al?Si?Al?4?Al?Si?4?B?C.?Si?4?Al?1186482?Li?112144?1mol?28+27+7?4=248g?AVM NN?10 3A(28277)4(10)aN?3310 3A(28277)4g cmg cm(10)aN?C?D.?Si?Al?Li?Si?Li?Si?3 pm4a?D?D?8?D?A?2?A?B?B

13、?C?B?Y?C?D?X?2?2Br?1 mol X?4 mol2Br?D?D?9?D?W?X?Y?Z?M?Y?Y?F?M?X?X?2?4?6?X?Y?W?X?X?Be?C?O?M?X?M?1?2?3?M?Na?Mg?Al?X?Be?M?Na?Y?F?M?Na?Z?Ne?Ne?X?C?M?Mg?Y?F?M?Mg?Z?Na?W?M?Y?Z?W+12=9+11?W?O?X?C?X?O?M?Al?Y?F?M?Al?Z?Na?Mg?Z?Na?W?M?Y?Z?W+13=9+11?W?N?Z?Mg?W?M?Y?Z?W+13=9+12?W?O?X?O?公众号【永久学堂】微信：yjxt6699?O O?快速更

14、新?5?14?6?14?W?N?X?O?Y?F?Z?Na?M?Al?A?W?N?X?O?Y?F?N?O?F?W?X?Y?A?B?X?O?Z?Na?2Na O?22Na O?-2?-1?B?C?Z?Na?M?Al?NaOH?3Al OH?3Al OH?C?D?X?O?M?Al?23Al O?23Al O?Al?D?D?10?D?A?a?b?A?B?B?C?Fe?C?D?HCl?D?D?11?D?A?A?B?“?”?1?B?C?“?”?C?D?pH=4?D?D?12?C?A?OH?A?B?1 mol2-24 S O?2 mol-e?NO?2-24S O?2N?1 mol2 N?4 mol-e?2

15、mol-e?0.5 mol2N?11.2 L2N?B?C?+H?+Na?C?D?-+2-32422HSO+2H=S O+2H O+2e?D?13?C?A?kk?A?B?CO2 mol?2 mol NO?CO?2x?2NO g+2CO g?22Ng+2COg?(mol)?2 2 1 0?(mol)?2x 2x x 2x?(mol)?2-2x 2-2x x+1 2x?(5-x)mol?P0 kPa?0.9P0 kPa?000.95-5pxp?x=0.5 mol?CO?NO?N2?CO2?1 mol?1 mol?1.5 mol?1 mol?4.5 mol?22222N(CO)NO(CO)kppKkp

16、p?200220001.510.90.97.54.54.5110.90.94.54.5ppppp?B?C?k?k?H?0?C?D?pV=nRT?p=cRT?D?C?14.?B?pOH?HCl?I?II?III?IV?7?14?8?14?33(XO)c?32(HXO)c?32(H XO)c?33(H XO)c?A?33H XO?Ka1=3+233(H)(H XO)(H XO)ccc?III?IV?3323(H XO)=(H XO)cc?Ka1=?+Hc=10-(14-4.8)=10-9.2?A?B?M?-3-233H XOXOcc?3233(H XO)1(XO)cc?32+2+2332+a2a3

17、33(H XO)(HXO)(H)(H)(H)1(XO)(HXO)(H)(H)cccccccccKK?+a2a3(H)cKK?a2a31pHlglg2KK?B?C?23KH XO?2233H XOHXOH?23HXO23?Ka2 10-12?23233H XO+H OH XOOH?33H XO33H XO?14w4.8h39.2a110=1010KKK?23H XO?C?D?pH=7?+HOHcc?323233(H XO)2(HXO)3(XO)(Cl)=(Na)ccccc?D?B?15?1?+332CH CHO+2 Ag NH+2OH?3432CH COO+NH+2Ag+3NH+H O?2?3?

18、4?1?+332CH CHO+2 Ag NH+2OH?3432CH COO+NH+2Ag+3NH+H O?-+332CH CHO+2 Ag NH+2OH?+3432CH COO+NH+2Ag+3NH+H O?2?3?b?+Ag?2?c?pH?c?c?NaOH?2?3AgNO?4?AgCl?AgCl?AgCl?16.?1?Si?2?3Fe OH?3Al OH?3Ga OH?5.5?pH?7?3?4Al OH?3Al OH?4?-234CO+Ga OHHCO=?3Ga OH?5?-4Ga OH+3e=Ga+4OH?6?1.01029.5?Ti?Si?3+Ga?3+Al?2+Fe?3+Fe?公众号【

19、永久学堂】微信：yjxt6699?TiTi?2+FeFe?快速更新?9?14?10?14?42FeSO7H O?3+Ga?3+Al?2+Fe?3+Fe?NaOH?pH?5.5?7?“?”?3Fe OH?3Al OH?3Ga OH?NaOH?3Al OH?3Ga OH?4Al OH?4Ga OH?3Fe OH?2CO?4Al OH?3Al OH?2CO?4Ga OH?3Ga OH?NaOH?3Ga OH?4Na Ga OH?4Na Ga OH?Ga?1000?3NH?GaN?1?Ti?Si?2?Si?2?“?”?3Fe OH?3Al OH?3Ga OH?0.1 mol/L?“?”?3+Ga?2+

20、Fe?pH?9.0?()OHc?=-51L.0 10mol/?sp2Fe OHK?552151(001)10?0.1 mol/L?()OHc?15100.1?mol/L?710m ol/L?pOH?7?pH?7?pH?5.5?pH?7?42FeSO7H O?3Fe OH?3Al OH?3Ga OH?5.5?pH?7?3?“?”?224323=2 Al OH+CO2Al OH+CO+H O?4Al OH?3Al OH?4?“?”?4Na Ga OH?2CO?3Ga OH?3NaHCO?-234CO+Ga OHHCO=?3Ga OH?-234CO+Ga OHHCO=?3Ga OH?5?4Na Ga

21、 OH?-4Ga OH+3e=?-Ga+4OH?-4Ga OH+3e=Ga+4OH?6?3+4Ga+4OH=Ga OH?K=?-43+4-Ga OHGaOHccc?=?-+43243+4-+432Ga OHNHNHH OGaOHNHNHH Occccccc?b32sp311NHH OGa OHKKK?=62.0 10?512.0 10?30.511.0 10?29.51.0 10?29.51.0 10?17.?1?0.75r?2?C?AC?3?2220(DVB)(H)(DEB)pppp?62.5%?1?1?2?(0.1)(0.1)2(0.1)(0.2)xyxyrkrk?y?1?1?3?(0.1

22、)(0.1)4(0.2)(0.1)xyxyrkrk?(0.1)(0.1x(0 1(0.2)(0.1x(0 1?x?2?3?331010rkr?4?3210(0.05)(0.3)0.75vrr?0.75r?2?5?5?C?A?B?C?AC?3?I?II?pK?T?10H?20H?DEB?DVB?120HHH?DEB?DVB?222002200(H)(DVB)()(DVB)(H)(DEB)(DEB)pppppppKpppp?20(H)2()2(H)2pp2(H)22p20p22()2p?2220(DVB)(H)(DEB)pppp22(H)22p20p?100 kPa?10 mol?1 mol?10

23、 kPa?11?14?12?14?A?I?lnpK?0?pK?1?I?200200(H)(EVB)(EVB)(H)1(DEB)(DEB)pppppppKpppp?20(H)2pp(H)21p01p2()21p?2(H):(DEB)2:1pp?p0?100 kPa?(EVB)50 kPap?(EVB)5 moln?(DVB)1.25 moln?2EVB(g)DVB(g)H(g)?DVB(g?mol?1.25 1.25 1.25 2DEB(g)EVB(g)H(g)?EVB(g?mol?1.25+5 1.25+5 1.25+5?DEB?1.255100%10?=62.5%?62.5%?18.?1?2

24、6s;?2?3sp?NH?334CH NH NH?334CH NH NH?3sp?NH?334CH NH NH?3?+33CH NH?I?+33CH NH?I?12?12?4?1?2+Pb?1?+33CH NH?3?I?321310cm a?A1 207 g/mol3 127 g/mol 1 32 g/molN?A620 g/molN?321310cm a?mV?2133A62010 g cma N?2133A62010 g cma N?5?1?2?3?14?14?34?14?14?34?+K?8?6?+K?+K?4?1?12?4?4?4?8?+K?26HfBr?118682?4?NA?A8

25、394 17824 80N?g?a nm?V?7310 cma?3 g cm?mV?37A8 394 17824 8010Na?g/cm3?a?3A8 394 17824 80N?710 nm?Hf?K?14?73A338394 17824 801044aN?nm?73A38394 17824 80104N?19?1?2?3?b?4?5?6?9?公众号【永久学堂】微信：yjxt6699 yjx快速更新?13?14?14?14?1?A?2?B?5?C?AB?B?CE?C?E?1?CD?D?3?GH?b?b?4?FG?H?GH?5?E+IJ?6?B?B?X?B?4?1?2?3?F?2NH?COOH?3?9?5?2:2:2:1:1?9?