2024高考化学密训卷（一）-试卷含答案.pdf

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1、?1?16?2?16?H 1 C 12 Sn 119 Cl 35.5?1?A?AG60E?B?“?”?C?EAST?“?”?EAST?D?0.03 mm?100?2?A?B?C?3NaHCO?D?3?A?3ZnCO?+2+322ZnCO+2HZn+CO+H O=?B?CO2?C?2Ca ClO?2SO?2+223Ca+ClO+SO+H O=CaSO+Cl+2H?D?44NH HSO?2Ba OH?2:1?2+244423=Ba+2OH+H+NH+SOBaSO+2H O+NH?4?BTK?A?262372C H N OB?C.?C?N?2sp?3sp?D.?5.?AN?A?22.24 L SO?

2、21.12 OL?A0.2NB?1.12 L HF?A5NC?0.5 L pH2?A0.01ND?42 g24 C H?36C H?C-H?A6N6.?A?3GaF?1000?3GaCl?78?0.00yjx?微信?堂】A快更新?“?3?16?4?16?B?222N O Cl?CpKa?22CHF COOHCHCl COOH?D?c(2-HA)D?c(3H A)+c(-2H A)+c(2-HA)+c(3-A)=0.1 mol/L?15?FTO?-?(PSCs)?4SnCl?FTO?4SnCl?Sn2SnCl4SnCl?/?232246?33?/?2260652114?Sn?3+Fe?2I?Sn

3、?22SnOH Ox?1?_?_?2?_?“?”?“?”?3?2Cl?Sn?4SnCl?2SnCl?_?_?9?16?10?16?4?_?5?4SnCl?2SnCl?4SnCl?m g?3224+FeSnFeSn224FSn22+22FeF2 2?250 mL?25.00 mL?10.1000 mol L?15.00 mL?4SnCl?_%(?m?)?4SnCl?_?272Cr O?Cl?16?“?”?S?Se?23Fe O?CuO?ZnO?2SiO?1?2?“?”?“?”?95?3?2ClO?2ClO?2ClO?2225NaClO4HCl=4ClO5NaCl2H O?32422224222N

4、aClOH SOH O2ClONa SO2=O=OH?2ClO?4?“?”?Se?23H SeO?Ka1?32.7 10?5?“?”?2+Cu?2+Zn?3+Fe?2ClO?23H SeO?22NHCS?“?”?2+Cu/Cu2+Zn/Zn2+Fe/Fe3+Fe/2+Fe2ClO/Cl?23H SeO/Se?/V0.345?0.760?0.4400.7701.5110.740?0.740 V?1.511V?“?”?23Na SO?V?23H SeO?2+Zn?+Na?6?“?”?i.?0.1 g?15 mL?1 mL?Se?23H SeO?ii.?3HNO?2NO?更更?11?16?12?16

5、?iii.?2 mL KI?5 mL?1 mol Lc?223Na S O?223Na S O?V mL?2322H SeO4KI4HCl=Se2I4KCl3H O?2223246=I2Na S ONa S O2NaI?232232462H SeO4Na S O4HCl=Se2Na S O4NaCl3H O?Se?M g/mol?7?“?”?23Na SeSO?2Na S?c(2-S)?10.0052 mol L?c(2+Cu)?Ksp(CuS)?361.3 10?17?“?”?2CO?4CH?I?2242COg4HgCHg2H O g?H1?1156.9 kJ mol?II?222COgHg

6、CO gH O g?H2?1?mfH?mfH?25?2CO?g?CO?g?2H O?g?mfH?1kJ mol?393.5?110.5?241.8?I?_?II?H2?_?2?_?A.?La?B.?Ni?23La O?223La O COC.2H?Ni?H*?D.23La O?3?2CO?2H?2CO?n(X)?T?Y?Z?1100 K?5 mol2 CO?10 mol2 H?15 kPa?10 min?p?2H O?5 kPa?p?CO?2 kPa?v?2H?-1kPa min?,?I?Kp?4?2CO?2CO?O?HCOOH?C?4CH?3CH OH?2CO?13?16?14?16?FE%

7、=XX100%QQ?XQ?nF?n?X?F?B?_?HCOOH?HCOOH?3CH OH?4CH?18?NA?1?Ti?_?_?2?Ti?_?a.?22Ar 4s 4p b.?21Ar 3d 4s c.?3Ar 3d d.?31Ar 3d 4s?3?2TiO?1843?4TiCl?-25?_?4?+Na?2+Fe?3+Fe?-CN?+Na?2+Fe?3+Fe?_?a pm?_ 3g/cm?19?1?A?2?B?3?EF?4?5?A?D?B?G?C?H?6?K?L?公众号【永久学堂】微信：yjxt6xt6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6

8、 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 66 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 69 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

9、 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 快速更新?快?15?16?16?16?R6?R7?H?K?1?2?2?HATU?n?2n?3n?L?n?L?1?14?2?14?1?

10、C?A?A?B?B?C?C?D?D?C?2?C?A?A?B?B?C?3NaHCO?C?D?D?C?3?A?A?3ZnCO?+2+322ZnCO+2HZn+CO+H O=?A?B?CO2?B?C?2Ca ClO?2SO?2+2Ca+2ClO+2SO+?+24242H O=CaSO+SO+2Cl+4H?C?D?-OH?+4NH?+H?+H?44NH HSO?2Ba OH?2?1?2+24=Ba+2OH+2H+SO?42BaSO+2H O?D?A?4?D?A?262372C H N O?A?B?B?C?N?2?3sp?2sp?3?3sp?2sp?sp?3sp?2sp?C?D?D?D?5?D?A?22

11、.24 L SO?0.1 mol?21.12 OL?0.05 mol?0.2 mol?2SO?2O?A?B?HF?Vm=22.4 L/mol?B?C?pH=2?c(+H)=0.01 mol/L?c(+H)=2c(2-4SO)?c(2-4SO)=0.005 mol/L?N(O)AcVN?公众号【永久学堂】微信：yjxt6699 快速更新?3?14?4?14?0.0050.54AN=0.01AN?0.01AN?C?D?24C H?36C H?2CH?42 g?3 mol2 CH?C-H?42 g24 C H?36C H?C-H?32AN=6AN?D?D?6?D?A?3GaF?3GaCl?3GaF?

12、3GaCl?3GaF?3GaCl?A?B?NN?O=O Cl-Cl?222N O Cl?B?C?FCl?2CHF COOH?pKa?22CHF COOH Ka2?L3?3-2(H A)(H A)cc?L4?22-(H A)(HA)cc?A?L3?X=3-2(H A)(H A)cc?A?B?Ka1=3.1310?410?B?C?Ka3=6.410?pH=6.4?c(3-A)=c(2-HA)?pH=6?c(3-A)c(2-HA)?C?D?c(3H A)+c(-2H A)+c(2-HA)+c(3-A)0.1 mol/L?D?B?15.?1?2?3?232?652?2SnCl?4?4222SnCl+2

13、 H O=SnOH O+4HClxx2H O+4H2?5?8.558551100%mm?2+4+22=2Sn+O+4H2Sn+2H O?1?HCl?HCl?2?3?2SnCl?652?4SnCl?114?Sn?232?Sn?2Cl?4SnCl?2SnCl?Sn?2Cl?4SnCl?2SnCl?232?652?652?2SnCl?4SnCl?4SnCl?232?652?2SnCl?4?4SnCl?4222SnCl+2 H O=SnOH O+4HClxx2H O+4H2H H?4222SnCl+2 H O=SnOH O+4HClxx2H O+4H2H H?5?32SnCl?62+Fe?2-27Cr

14、 O-?2SnCl?250ml0.015L 0.1mol/L 3190g/mol25mlgm?100%=855m%?2+2=2Sn+O+4H4+22Sn+2H O?8.558551100%mm?2+4+22=2Sn+O+4H2Sn+2H O?16?1?2?95?95?3?2ClO?4?2SiO?5?+22ClO+4H+5eCl=+2H O?3+2+Fe+e=Fe?0.345?0.740?2-2-23342H SeO+2SO=2SO+Se+H O?2+Fe?2+Cu?6?3100.1 4cVM?100%?9?14?10?14?7?34-12.5 10mol L?S?Se?23Fe O?CuO?Z

15、nO?2SiO?S?+34ClO+4H+Se=?24ClO+?2H O+23H SeO?23Fe O?CuO?ZnO?2SiO?3+Fe?2+Cu?2+Zn?23H SeO?+Na?24SO?23Na SO?23H SeO?Se?3+Fe?2+Fe?0.345?0.740?2+Cu?2+Zn?2+Fe?+Na?24SO?Se?1?2?S?S?95?95?3?2ClO?2ClO?2ClO?2O?2ClO?2ClO?4?2SiO?2SiO?5?23Na SO?0.740?1.511V?“?”?2ClO?3+Fe?2ClO?Cl?+22ClO+4H+5eCl=+2H O?3+Fe?2+Fe?3+2+

16、F=+e=eFe?+22ClO+4H+5eCl=+2H O?3+2+F=+e=eFe?0.740?0.345?23H SeO?Se?4?2-3SO?2?2-4SO?1:2?2-2-23342H SeO+2SO=2SO+Se+H O?2+Cu?2+Zn?2+Fe?+Na?0.345?0.740?2-2-23342H SeO+2SO2SO+Se+H O?6?23H SeO?Se?22I?423Na SO?-31 mol/L10 L g/mol40.1 gcVM?100%?-3100.1 4cVM?100%?3100.1 4cVM?100%?7?c(2-S)?0.0052 molL?1?c(Cu2+

17、)?c(2+Cu)?sp2-CuSSKc?361.3 100.0052?mol/L?2.510?34 molL?1?341 2.5 10mol L?17.?1?-141.2 kJ mol?2?C?3?CO?I?II?I?n(2CO)?II?n?2CO?0.8?2516?4?2CO2e2HHCOOH?4:8:3?1?I?H1?0?S?0?G=H-TS?0?T?I?21C s+O g=CO g2 H3?1110.5 kJ mol?22C s+Og=COg H4?1393.5 kJ mol?2221Hg+Og=H O g2?快更新?11?14?12?14?H5?1241.8 kJ mol?222CO

18、g+HgCO g+H O g?H2?H3?H4+H5?-141.2 kJ mol?2?23La O?La?+3?23La O?La?+3?A?Ni?23La O?223La O CO?B?2H?Ni?H*?HH?C?D?C?3?I?II?I?4CH?II?CO?Y?CO?Z?2CO?I?n?2CO?II?n?2CO?5 mol2 CO?10 mol2 H?15 mol?15 kPa?10 min?p?2H O?5 kPa?p?CO?2 kPa?222COg+HgCO g+H O g?kPa?2 2 2 2?2242COg+4HgCHg+2H O g?(kPa)1.5 6 1.5 3?p?2H?

19、=?2+6?kPa=8 kPa?22(H)8 kPa(H)10 minpvt?0.8 kPamin?1?241.5 5251.5216pK?4?A?O?B?B?2CO2e2HHCOOH?HCOOH?3CH OH?4CH?10%?60%?30%?1 mol HCOOH?2 mol?1 mol 3CH OH?6 mol?1 mol 4CH?8 mol?HCOOH?3CH OH?4CH?10%60%30%:4:8:3268?18.?1?223d 4s?12?2?b?3?2TiO?4TiCl?4?+2?10 3A23 456 826 24(a 10)N?1?Ti?223d 4s?1s?2s?2p?3s

20、?3p?3d?4s?15?Ti?3d?2?2?Ti?1+1+3+1+3+2+1=12?223d 4s?12?2?a?d?Ti?a?ac?b?Ti?bd?b?b?3?2TiO?4TiCl?2TiO?4TiCl?4?-CN?11242462442?Fe?111861218824?+Na?8?3NaFe CN?-CN?1?+Na?+1?Fe?+2?+2?1?+Na?4?Fe?111861218824?-CN?11242462442?a pm?10 3A23 456 82624(10)aN?g/cm3?10 3A23 456 82624(10)aN?19.?1?2?13?14?14?14?3?4?5?C?6?1?A?2?AC?AB?B?3?EF?E?1?F?4?5?A.?E?D?A?B.G?B?C.H?C?C?6?K?1?R?COOCH3R?COOH?1?1?2?2?2?HATU?n?2n?3n?COONa?L?n?L?：9?B B?快速更新?公众号【永久学堂】微信：yjxt6699?永久学堂】微信：yjxt6699 学堂】微信：yjxt6699?快速更新